Based on the standard reduction potentials in Table 2, which of the following metals could provide cathodic protection to iron: Al, Cu, Ni, Zn?
Based on the standard reduction potentials in Table 2, which of the following metals could provide cathodic protection to iron: Al, Cu, Ni, Zn?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Based on the standard reduction potentials in Table 2, which of the following metals could
provide cathodic protection to iron: Al, Cu, Ni, Zn?

Transcribed Image Text:Table 2. Standard Reduction Potentials at 25 °C.
Half-Reaction
E°(V)
→ 2F¯(aq)
F-(g) + 2e¯
O;(g) + 2H*(aq) + 2e¯
Co*(aq) + e¯
H,O,(aq) + 2H*(aq) + 2e
PhO,(s) + 4H*(aq) + SO (aq) + 2e → PhSO,(s) + 2H;O
Ce*(aq)
MnO, (aq) + 8H*(aq) + 5e¯
Au"(aq) + 3e¯
Cl,(g) + 2e
Cr,03 (aq) + 14H*(aq) + 6e¯ → 2Cr*(aq) + 7H,O
MnO,(8) + 4H' (aq) + 2e¯
0,(g) + 4H*(aq) + 4e¯ → 2H,O
Br,(l) + 2e → 2Br¯(aq)
NO, (aq) + 4H*(aq) + 3e¯
2H9²*(aq) + 2e
Hgž*(aq) + 2e™
Ag*(aq) + e¯
Fe" (aq) + e
0,(g) + 2H*(aq) + 2e
MnO, (aq) + 2H;O + 3e
1-(8) + 2e™
0,(g) + 2H,0 + 4e
Cu²*(aq) + 2e¯
AgCl(s) + e¯
so, (aq) + 4H*(aq) + 2e¯ → SO;(g) + 2H¿O
Cu²*(aq) + e¯
Sn** (aq) + 2e
2H*(aq) + 2e¯
Pb2* (aq) + 2e
Sn2*(aq) + 2e¯
Ni*(aq) + 2e
Со* (аq) + 2е
PbSO,(s) + 2e
C* (aq) + 2e¯
Fe*(aq) + 2e¯
Cr*(aq) + 3e'
Zn* (aq) + 2e¯
2H‚0 + 2e
Mn* (aq) + 2e¯
Al" (aq) + 3e
Be* (aq)
Mg*(aq) + 2e
Na*(aq) + e¯
Ca*(aq)
S*(ag) + 2e
Ва (аq) + 2е-
K*(ag) + e
+2.87
+2.07
→ 02(g) + H2O
Co*(aq)
+1.82
2H,0
+1,77
+1,70
Ce*(aq)
+1.61
e
Mn²*(aq) + 4H,O
+1.51
Au(s)
+1.50
→ 2CI (aq)
+1.36
+1.33
+1.23
→ Mn²" (aq) + 2H,O
+1.23
+1.07
NO(g) + 2H,O
+0.96
→ Hgž*(aq)
2Hg(l)
Ag(s)
Fe²* (aq)
+0.92
+0.85
+0,80
+0.77
→ H,O,(aq)
MnO,(8) + 40H (aq)
+0.68
+0.59
21°(aq)
+0,53
40H¯(aq)
+0.40
Cu(s)
+0.34
Ag(s) + CI¯(aq)
+0,22
+0.20
+0.15
Cu*(aq)
• Sn²* (aq)
+0,13
H(g)
0.00
Pb(s)
-0.13
• Sn(s)
-0.14
Ni(s)
-0.25
Co(s)
-0.28
Pb(s) + SO; (aq)
-0,31
Cd(s)
-0.40
-0.44
Fe(s)
Cr(s)
-0.74
► Zn(s)
H2(g) + 20H (aq)
· Mn(s)
Al(s)
► Be(s)
Mg(s)
-0.76
-0,83
-1.18
-1.66
2e
-1.85
-2.37
-2.71
-2.87
Na(s)
2e
► Ca(s)
Srís)
-2.89
» Ba(s)
- K(s)
-2.90
-2.93
Li*(aq) + e
► Li(s)
-3.05
НАЕ
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