(b) Use the listing of standard reduction potentials on page 10 to determine the E° for Ce**(aq) + 4e → Ces) Reduction half reaction E/V Reduction half reaction E/V +0.80 +0.54 Ag Ag Agir+ Ag+ Br +1.98 +0.53 -0.14 In' +rIn In+ In In+ 2eIn In"+ eIn In ln +0.0713 +0.22 -0.40 ARCO, + 2e2Ag+ Cro AgF+e Ag+ F Agl eAg+r A+ Al +0.45 -0.44 +0.78 -0.34 --0.15 -0.49 -2.93 -2.52 --1.66 K+K Au +e Au Au+ Au 1.69 La+ la +1.40 -3.05
(b) Use the listing of standard reduction potentials on page 10 to determine the E° for Ce**(aq) + 4e → Ces) Reduction half reaction E/V Reduction half reaction E/V +0.80 +0.54 Ag Ag Agir+ Ag+ Br +1.98 +0.53 -0.14 In' +rIn In+ In In+ 2eIn In"+ eIn In ln +0.0713 +0.22 -0.40 ARCO, + 2e2Ag+ Cro AgF+e Ag+ F Agl eAg+r A+ Al +0.45 -0.44 +0.78 -0.34 --0.15 -0.49 -2.93 -2.52 --1.66 K+K Au +e Au Au+ Au 1.69 La+ la +1.40 -3.05
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:(b) Use the listing of standard reduction potentials on page 10 to determine the
E° for Ce**(aq) + 4e
→ Ce(s)
Reduction half-reaction
E/V
Reduction half-reaction
E/V
Ag Ag
Age Ag
Agir + Ag+ Br
AgCleAg+a
1+ 2e21
15+2e3r
In'+eIn
In+e In
In + 2e In
In"+ SeIn
In" In
K*+ K
La+ ela
Li
Mg+ 2- Mg
Mn"+ 2e Mn
Mn+e Mn
MnO, + 4+ 2e- Ma + 2H,o
MnO; + SH + Se Mn+ 4H,0
MnO; +eMno}-
Mno + 21,0+ 2eMno, + 4OH
Na' +e Na
NP+ 2e NI
NIOOH + H,0+ Ni(OH), +OH
NO;+2H+e NO, + H,0
NO; + H+ - NO+ 2H,0
NO; + H,0+ 2e- NO; + 20H
O,+2H,0+ de-→ 4OH
0,+ 4H+ de 2H,0
40.80
+0.54
+1.98
+0.53
+0.0713
-0.14
+0.22
-0.40
AgCro, + 2e 2Ag+ Cro
AgF+e Ag +F
Agl + Ag+ r
Al+ Se Al
+0.45
-0.44
+0.78
-0.34
-0.15
-0.49
-1.66
-2.93
Au' +eAu
Au+ Se Au
Ba+ 2e-Ba
Be+ 2eBe
+1.69
-2.52
+1.40
-3.05
+2.91
-2.36
-L8S
-1.18
+0.20
+1.51
Br, + 2e 2Br
Bro +H,0+ 2e Br+ 20H
Cal+ 2eCa
Ca(OH), + 2e Cd+ 20H
Ca + 2eCd
Ce+ Ce
+1.09
+1.23
+0.76
+1.51
-2.87
+0.56
-0.81
+0.60
-0.40
-2.71
-2.48
-0.23
CeteCe"
+1.61
+0.49
a,+ 2e-2
CIO +H,0+ 2→a+20H
CO;+ 2H+ 2e →do; + H,0
do; +H,0+2 do; + 20H
Co+ 2Co
CorCo
C+2 Cr
Cr,O+14H+ 6e 20+ 7H,0
C+ Cr
+1.36
-0.80
+0.89
+0.96
+1.23
+0.10
+0.36
+0.40
-0.28
+1.23
+1.81
-0.56
0,+1,0+2e HO; +OH
0,+ 2H + 2e0, +H,O
0,+H,0+2e-0, + 20H
Ph+ 2 Pb
Pb+ 2e P
-0.91
-0.08
+1.33
+2.07
-0.74
+1.24
0.41
-0.13
-2.92
+1.67
Cu+ Cu
Cu"+ 2 Cu
Cu Cu
F,+2e2F
Fe+ 2e Fe
Fe"+eFe
Fe+Fe
PbSo, + 2e Pb so
Pr+ 2e Pr
Pu+ePu
Ra+ 2e Ra
+0.52
-0.36
+0.34
+1.20
+0.16
+0.97
+2.87
-2.92
-0.44
Rb+eRb
-2.93
-0.04
S+ 2 S
-0.48
s,o+ 2e 25o
Sc+ 3e Se
40.77
+2.05
(FelCN),+ (Fe(CN),
21+ 2H,
21,0+ 2H, + 20H
2HBrO+ 2H + 2eBr, + 21,0
2HCIO+ 2H+ 2ea,+ 2H,0
H,O, + 2H+2e 2H,0
H,XeO, + 2H + 2er XeO, +3H,0
Hg + 2e2Hg
Hg,Cl,+ 22Hg+ 2C
Hg+ 2e Hg
+0.36
-2.09
0, by definition
Sn+ 2e Sn
-0.14
-0.R3
Sn+ 2
Sn
+0.15
e
Sr+ 2e Sr
TP+ 2eTi
+1.60
-2.89
+1.63
-1.63
+1,78
-0.37
+3.0
0,00
+0.79
-0.34
U+ U
Ut U
y+ 2eV
+0.27
-1.79
+0.86
--0.61
+0.92
-1.19
Hg,SO, + 2 2Hg+ So
+0.62
--0.26
Za+ 2eZn
-0.76
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