Consider the standard reduction potentials and redox couples used in a galvanic cell. Unbalanced Half-Reaction E(V) MnO4 (aq) + 3e → MnO2(s) (at basic pH) 0.59 Fe3 (aq) + e Fe2*(aq) > 0.77 What is the balanced reaction taking place in the cell (in basic solution)? 2 H20(1) + MnO4 (aq) + 3 Fe3+(aq) 3 Fe2*(aq) + MnO2(s) + 4 OH- - MnO2(s) + 4 OH¯ + 3 Fe3+(aq) 3 Fe2+(aq) + 2 H20(1) + MnO4¯(aq) > O 3 Fe2*(aq) + 2 H2O(1) + MnO4 (aq) MnO2(s) + 4 OH¯ + 3 Fe3+(aq) - 3 Fe2*(aq) + MnO2(s) + 4 OH- 2 H20(1) + MnO4 (aq) + 3 Fe3+(aq)

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Chapter1: Chemical Foundations
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Consider the standard reduction potentials and redox couples used in a galvanic cell.
Unbalanced Half-Reaction
E°(V)
MnO4 (aq) + 3e MnO2(s)
(at basic pH)
0.59
Fe3+(aq) + e-
Fe2*(aq)
0.77
What is the balanced reaction taking place in the cell (in basic solution)?
2 H20(1) + Mn04 (aq) + 3 Fe3+(aq)
→ 3 Fe2*(aq) + MnO2(s) + 4 OH-
MnO2(s) + 4 OH¯ + 3 Fe3+(aq)
3 Fe2+(aq) + 2 H20(1) + MnO4¯(aq)
MO 3 Fe2*(aq) + 2 H2O(1) + MnO4¯(aq)
MnO2(s) + 4 OH¯ + 3 Fe3+(aq)
M 3 Fe2+(aq) + MnO2(s) + 4 OH → 2 H20(1) + MnO4 (aq) + 3 Fe3+(aq)
Transcribed Image Text:Consider the standard reduction potentials and redox couples used in a galvanic cell. Unbalanced Half-Reaction E°(V) MnO4 (aq) + 3e MnO2(s) (at basic pH) 0.59 Fe3+(aq) + e- Fe2*(aq) 0.77 What is the balanced reaction taking place in the cell (in basic solution)? 2 H20(1) + Mn04 (aq) + 3 Fe3+(aq) → 3 Fe2*(aq) + MnO2(s) + 4 OH- MnO2(s) + 4 OH¯ + 3 Fe3+(aq) 3 Fe2+(aq) + 2 H20(1) + MnO4¯(aq) MO 3 Fe2*(aq) + 2 H2O(1) + MnO4¯(aq) MnO2(s) + 4 OH¯ + 3 Fe3+(aq) M 3 Fe2+(aq) + MnO2(s) + 4 OH → 2 H20(1) + MnO4 (aq) + 3 Fe3+(aq)
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