Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:**Question:**
A nucleus that is shielded will appear ______ in the NMR spectrum.
**Options:**
A) downfield
B) upfield
---
In the context of NMR (Nuclear Magnetic Resonance) spectroscopy, a shielded nucleus will appear upfield in the spectrum. The concept of shielding refers to the electron density around a nucleus, which affects the magnetic environment experienced by the nucleus. Higher electron density around a nucleus provides more shielding, causing the NMR signal to appear at a higher chemical shift value, or "upfield."
**Explanation of Terms:**
- **Upfield:** Refers to the higher frequency (lower energy) side of the NMR spectrum, typically represented by a lower chemical shift value.
- **Downfield:** Refers to the lower frequency (higher energy) side of the NMR spectrum, usually represented by a higher chemical shift value.
In summary, in NMR spectroscopy, shielded nuclei resonate at lower chemical shift values, appearing upfield in the spectrum.
Expert Solution
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Step 1
Shielded nucleus means electromagnetic field applied is not experienced as much by nucleus as it is applied their is shield of electrons in between them due to which nucleus experience less electromagnetic field.
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