Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
Please help me answer 4. Answer on bracket. Thank you.
![11:01 AM Wed Nov 4
* 45%
年
20863710 PDF
1. A constant direct current of 0.027 A flows through an silver coulometer for a period
of 1 hour. Calculate the weight of silver deposited in the coulometer.
[0.109]
A constant direct current was passed through a solution of copper sulfate, CUSO4, for
1 h, and 0.040 g of copper was deposited. What much was the current passed?
2.
[0.034]
3. A constant current flows for 3.75 h through two electrolytic cells connected in series.
One contains a solution of AgNO3, and the second a solution of CuCl2. During this
time, 2.00 g silver are deposited in the first cell. How many grams
deposited in the second cell?
[0.589]
of
copper are
4. An electrolytic cell containing ZnSO4 solution was connected in series with a cell
containing NaOH solution. When a constant current was passed through the circuit
for set period of time, 418 cm³ (measured at STP) was liberated in the cell containing
NaOH solution. How many grams of Zn would have been deposited in the cell
containing ZnSO4 solution?
[0.610]](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F32ed39b1-5bf1-4044-9c10-eb2239775fbe%2Faca512be-9d64-4a56-a2b6-9f51a28be67a%2Fdmoiddn_processed.png&w=3840&q=75)
Step by step
Solved in 4 steps
