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Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc

Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc
Transcribed Image Text:Another useful aspect of Pd(0)-catalyzed allylic alkylation is the ability to take reactants that are meso and desymmetrize them in the resulting products through the addition of a chiral ligand for the Pd metal. Draw the two n-allylic complexes formed in this reaction of the following reactant with PdL,. Describe why chirality in a ligand L would influence the preference for one of these complexes over the other. AcO OAc
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