An unknown compound has the mass spectrum shown here. Its 13C NMR spectrum has four signs and its IR spectrum has an intense peak near 1720 cm-1. Propose a structure for this compound. 100- 80- 60어 m/z = 152, 40- m/z = 150, 20- 40 80 120 160 m/z
An unknown compound has the mass spectrum shown here. Its 13C NMR spectrum has four signs and its IR spectrum has an intense peak near 1720 cm-1. Propose a structure for this compound. 100- 80- 60어 m/z = 152, 40- m/z = 150, 20- 40 80 120 160 m/z
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Mass Spectrometry Analysis of an Unknown Compound**
An unknown compound has been analyzed using mass spectrometry, and the resulting spectrum is shown below. The compound's spectroscopic data includes:
- A mass spectrum with specific peaks.
- A ^13C NMR spectrum showing four signals.
- An IR spectrum displaying an intense peak near 1720 cm^-1.
**Mass Spectrum Details:**
The mass spectrum shows the relative abundance of ions of different mass-to-charge ratios (m/z). Notable features in this spectrum include:
- A significant peak at m/z = 152.
- A smaller peak at m/z = 150.
These peaks are indicated on the graph with dashed lines pointing to the respective m/z values.
**Graph Explanation:**
- **X-axis (m/z):** Represents the mass-to-charge ratio of detected ions in the sample.
- **Y-axis (Relative abundance):** Indicates the relative abundance or intensity of the detected ions.
The peak at m/z = 152 suggests a molecular ion or a fragment ion with this specific mass-to-charge ratio. The smaller peak at m/z = 150 likely represents a related ion or a fragment.
**Further Spectroscopic Data:**
- **13C NMR Spectrum:** Four signals indicate the compound likely has four distinct carbon environments.
- **IR Spectrum:** The intense peak near 1720 cm^-1 typically corresponds to a carbonyl group (C=O).
**Conclusion:**
Based on the mass spectrum, 13C NMR signals, and the IR spectrum, propose a structure for this compound. Consider the presence of a carbonyl group and the molecular ion peak in determining the compound's structure.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F206206aa-1104-4dbc-9e08-21639f631eee%2F35596a60-ab5a-40dc-8c9a-4f817f8e102b%2Fvid7kba_processed.png&w=3840&q=75)
Transcribed Image Text:**Mass Spectrometry Analysis of an Unknown Compound**
An unknown compound has been analyzed using mass spectrometry, and the resulting spectrum is shown below. The compound's spectroscopic data includes:
- A mass spectrum with specific peaks.
- A ^13C NMR spectrum showing four signals.
- An IR spectrum displaying an intense peak near 1720 cm^-1.
**Mass Spectrum Details:**
The mass spectrum shows the relative abundance of ions of different mass-to-charge ratios (m/z). Notable features in this spectrum include:
- A significant peak at m/z = 152.
- A smaller peak at m/z = 150.
These peaks are indicated on the graph with dashed lines pointing to the respective m/z values.
**Graph Explanation:**
- **X-axis (m/z):** Represents the mass-to-charge ratio of detected ions in the sample.
- **Y-axis (Relative abundance):** Indicates the relative abundance or intensity of the detected ions.
The peak at m/z = 152 suggests a molecular ion or a fragment ion with this specific mass-to-charge ratio. The smaller peak at m/z = 150 likely represents a related ion or a fragment.
**Further Spectroscopic Data:**
- **13C NMR Spectrum:** Four signals indicate the compound likely has four distinct carbon environments.
- **IR Spectrum:** The intense peak near 1720 cm^-1 typically corresponds to a carbonyl group (C=O).
**Conclusion:**
Based on the mass spectrum, 13C NMR signals, and the IR spectrum, propose a structure for this compound. Consider the presence of a carbonyl group and the molecular ion peak in determining the compound's structure.
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