An optically active alcohol, A, C4H100 reacts with concentrated H2SO, at 180 °C to form compound B which can exist as cis-trans isomers. Compond A reacts with hot acidified KMNO4 to produce compound C which can reacts dinitrophenylhydrazine but does not react with Tollen's reagent. The reaction between C and Grignard reagent D yields compound E upon hydrolysis. The 8. with 2,4 structural formula for E is as follows: OH H3C-CH2-C-CH3 H3C-C-CH3 Determine the structure A, B, C and D with appropriate reason.

An optically active alcohol, A, C4H100 reacts with concentrated H2SO, at 180 °C to form compound B which can exist as cis-trans isomers. Compond A reacts with hot acidified KMNO4 to produce compound C which can reacts dinitrophenylhydrazine but does not react with Tollen's reagent. The reaction between C and Grignard reagent D yields compound E upon hydrolysis. The 8. with 2,4 structural formula for E is as follows: OH H3C-CH2-C-CH3 H3C-C-CH3 Determine the structure A, B, C and D with appropriate reason.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Organomagnesium compounds

The interaction of alkyl halide with Mg metal in a suitable ether solvent is the common method for the synthesis of the Grignard reagent.

Hydrolysis Grignard Reactions and Reduction

Organomagnesium halides are Grignard reagents. Francois Auguste Victor Grignard, a French chemist who received the Nobel Prize in Chemistry in 1912, created these highly useful reagents.

Question

8.
An optically active alcohol, A, C,H10O reacts with concentrated H2SO4 at 180 °C to
form compound B which can exist as cis-trans isomers. Compond A reacts with hot
acidified KMNO4 to produce compound C which can reacts
dinitrophenylhydrazine but does not react with Tollen's reagent. The reaction
between C and Grignard reagent D yields compound E upon hydrolysis. The
with 2,4
structural formula for E is as follows:
OH
H3C-CH2-C-CH3
H3C-C-CH3
Determine the structure A, B, C and D with appropriate reason.

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