An extremely soluble salt is added to water, and all of it dissolves. Is it at equilibrium? Explain 4b. A slightly soluble salt is added to water, and some of it dissolves. Is it at equilibrium? Explain 4c. Liquid water and water vapor reach equilibrium only in a closed container. Why?
An extremely soluble salt is added to water, and all of it dissolves. Is it at equilibrium? Explain 4b. A slightly soluble salt is added to water, and some of it dissolves. Is it at equilibrium? Explain 4c. Liquid water and water vapor reach equilibrium only in a closed container. Why?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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4a. An extremely soluble salt is added to water, and all of it dissolves. Is it at equilibrium? Explain
4b. A slightly soluble salt is added to water, and some of it dissolves. Is it at equilibrium? Explain
4c. Liquid water and water vapor reach equilibrium only in a closed container. Why?

Transcribed Image Text:The Ins and Outs
of Équilibrium
If you leave a closed, partly filled bottle of water in the sunlight, before
long you will observe water droplets near the top of the bottle and in the
neck. How did they get there? As the sun shines on the bottle, the water
begins to evaporate. As the number of vapor molecules increases, so does
the chance that they will interact with each other and recondense to form
water. This is how the water droplets get to the top of the bottle.
Changing phase is a reversible process. In a closed container, as the
amount of vapor increases and the amount of liquid decreases, the rate of
condensation increases and the rate of vaporization decreases. Eventually
the two rates become equal. When the rate of vaporization is equal to the
rate of condensation, the amount of vapor and the amount of liquid stops
changing. This is called equilibrium. Just because the rate of vaporization
and condensation is equal at equilibrium, it doesn't mean that the amount
of vapor and the amount of liquid is equal. For example, the amount of gas
at equilibrium will be greater at a high temperature than at a low
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The social dynamics of phase equilibrium
temperature.
There are other kinds of equilibrium besides phase equilibrium. Some chemical reactions are reversible and reach
equilibrium too. When undissolved solid sits at the bottom of a saturated solution, there is solution equilibrium. It may look
like the same undissolved solid at the bottom of the container the entire time, but dissolved material comes out of solution and
new material dissolves continuously. Only the amount ofundissolved material remains the same. This is often called dynamic
equilibrium because there is constant activity although there is no real change.
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