An electrochemical cell utilizes the following redox reaction NH4 + (ag) + 8Ce4*(ag) + 3H2O(I) → NO3- (ag) + 8Ce3*(ag) + 10H* (ag) Where the relevant half-reactions are: NO3 - (ag) + 10H* (ag) + 8e- → NH4 * (ag) + 3H2O Ce**(ag) + e- → Ce³*(ag) Ece = +0.88 V Ecel = +1.72 V 1. Calculate Ecu(not under standard conditions) when [NH4 1= 0.35 M, [Ce**] = 0.25 M, [NO3 -1= 5.0 x10-2 M, [Ce3+] = 6.0 ×10-2 M, and the [H*] = 1.0 x10-3 M

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
An electrochemical cell utilizes the following redox reaction
NHa * (ag) + 8Ce4"(ag) + зн-0() > NO; (ag) + 8Ce3"(ag) + 10н* (ag)
Where the relevant half-reactions are:
NO3 - (ag) + 1OH+ (ag) + 8e- → NH4 + (ag) + 3H20
Ce**(ag) + e- > Ce3*(ag)
Ecel = +0.88 V
Ecel = +1.72 V
1. Calculate Ec(not under standard conditions) when [NH4 +1 = 0.35 M, [Ce**] = 0.25 M,
[NO3 -1= 5.0 x10-2 M, [Ce3+] = 6.0 ×10-2 M, and the [H*] = 1.0 x10-3 M
2. How is Ecel, impacted when the concentration of H* (ag) is reduced? In other words, what
happens when the pH decreases? Provide reasoning to support your answer.
Transcribed Image Text:An electrochemical cell utilizes the following redox reaction NHa * (ag) + 8Ce4"(ag) + зн-0() > NO; (ag) + 8Ce3"(ag) + 10н* (ag) Where the relevant half-reactions are: NO3 - (ag) + 1OH+ (ag) + 8e- → NH4 + (ag) + 3H20 Ce**(ag) + e- > Ce3*(ag) Ecel = +0.88 V Ecel = +1.72 V 1. Calculate Ec(not under standard conditions) when [NH4 +1 = 0.35 M, [Ce**] = 0.25 M, [NO3 -1= 5.0 x10-2 M, [Ce3+] = 6.0 ×10-2 M, and the [H*] = 1.0 x10-3 M 2. How is Ecel, impacted when the concentration of H* (ag) is reduced? In other words, what happens when the pH decreases? Provide reasoning to support your answer.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Electrochemical Cells
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
  • SEE MORE QUESTIONS
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY