am al [1]o, the radical concentration varies with time according to'the following expression exp[(16fk,k, [I]o)t] exp[(16fkgk, [I],)¾t] + 1 [M ] 1 [M·]s Calculate [M•], and the time required for the free-radical concentration to reach 99% of this value using the following as typical values for constants and concen trations: ka = 1.0 X 10-4 sec-1, k, = 3 X 107 liter mol-1 sec-1,f= ½, and [I]o = 10-3 M. Comment on the assumption [I] = [I], that is made in deriving the non-stationary-state equation. S %3D %3D %3D
am al [1]o, the radical concentration varies with time according to'the following expression exp[(16fk,k, [I]o)t] exp[(16fkgk, [I],)¾t] + 1 [M ] 1 [M·]s Calculate [M•], and the time required for the free-radical concentration to reach 99% of this value using the following as typical values for constants and concen trations: ka = 1.0 X 10-4 sec-1, k, = 3 X 107 liter mol-1 sec-1,f= ½, and [I]o = 10-3 M. Comment on the assumption [I] = [I], that is made in deriving the non-stationary-state equation. S %3D %3D %3D
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
![am al [1]o, the
radical concentration varies with time according to'the following expression
exp[(16fk,k, [I]o)t]
exp[(16fkgk, [I],)¾t] + 1
[M ]
1
[M·]s
Calculate [M•], and the time required for the free-radical concentration to reach
99% of this value using the following as typical values for constants and concen
trations: ka = 1.0 X 10-4 sec-1, k, = 3 X 107 liter mol-1 sec-1,f= ½, and
[I]o = 10-3 M. Comment on the assumption [I] = [I], that is made in deriving
the non-stationary-state equation.
S
%3D
%3D
%3D](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fd1229a22-a413-4ad1-a52e-be0231cf1f58%2F4b5c4bd5-abf9-4eee-a7d6-2977605897a1%2Fughcj9h.png&w=3840&q=75)
Transcribed Image Text:am al [1]o, the
radical concentration varies with time according to'the following expression
exp[(16fk,k, [I]o)t]
exp[(16fkgk, [I],)¾t] + 1
[M ]
1
[M·]s
Calculate [M•], and the time required for the free-radical concentration to reach
99% of this value using the following as typical values for constants and concen
trations: ka = 1.0 X 10-4 sec-1, k, = 3 X 107 liter mol-1 sec-1,f= ½, and
[I]o = 10-3 M. Comment on the assumption [I] = [I], that is made in deriving
the non-stationary-state equation.
S
%3D
%3D
%3D
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