Acetylene and oxygen react to form carbon dioxide and water, like this: 2C₂H₂(g) +50₂(g) → 4CO₂(g) + 2H₂O(g) Suppose a mixture of C₂H₂, O₂, CO₂ and H₂O has come to equilibrium in a closed reaction vessel. Predict what change, if any, the perturbations in the below will cause in the composition of the mixture in the vessel. Also decide whether the equilibrium shifts to the right or left. perturbation Some H₂O is removed. Some O₂ is added. change in composition The pressure of C₂H₂ will The pressure of O₂ will The pressure of C₂H₂ will The pressure of CO₂ will ? ? ? ? shift in equilibrium to the right O to the left O (none) O to the right O to the left O (none) X 3

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**Using Le Chatelier's Principle to Predict the Result of Changing Conditions in a Chemical Equilibrium**

**Reaction:**  
Acetylene and oxygen react to form carbon dioxide and water, as shown:  
\[ 2 \text{C}_2\text{H}_2(g) + 5\text{O}_2(g) \rightleftharpoons 4\text{CO}_2(g) + 2\text{H}_2\text{O}(g) \]

**Scenario:**  
Suppose a mixture of \(\text{C}_2\text{H}_2\), \(\text{O}_2\), \(\text{CO}_2\), and \(\text{H}_2\text{O}\) has come to equilibrium in a closed reaction vessel. Predict the change, if any, due to the following perturbations in the table, and determine whether the equilibrium shifts to the right or to the left.

| Perturbation                          | Change in Composition | Shift in Equilibrium |
|---------------------------------------|-----------------------|----------------------|
| Some \(\text{H}_2\text{O}\) is removed. | ?                     | ☐ to the right  ☐ to the left ☐ (none) |
| The pressure of \(\text{O}_2\) will:     | ?                     | ☐ to the right  ☐ to the left ☐ (none) |
| Some \(\text{O}_2\) is added.          | ?                     | ☐ to the right  ☐ to the left ☐ (none) |
| The pressure of \(\text{CO}_2\) will:     | ?                     | ☐ to the right  ☐ to the left ☐ (none) |

**Explanation & Discussion:**  
Use Le Chatelier's Principle to evaluate how the system responds to each change. For example, removing \(\text{H}_2\text{O}\) might shift the equilibrium towards the products to restore balance, while adding \(\text{O}_2\) could push the equilibrium to the right to consume the excess reactants.

**Action:**  
- Review each scenario.
- Predict and check your answers using the principles of chemical equilibrium.

**Note:**  
This is a hypothetical exercise to aid in understanding equilibrium responses in chemical reactions.
Transcribed Image Text:**Using Le Chatelier's Principle to Predict the Result of Changing Conditions in a Chemical Equilibrium** **Reaction:** Acetylene and oxygen react to form carbon dioxide and water, as shown: \[ 2 \text{C}_2\text{H}_2(g) + 5\text{O}_2(g) \rightleftharpoons 4\text{CO}_2(g) + 2\text{H}_2\text{O}(g) \] **Scenario:** Suppose a mixture of \(\text{C}_2\text{H}_2\), \(\text{O}_2\), \(\text{CO}_2\), and \(\text{H}_2\text{O}\) has come to equilibrium in a closed reaction vessel. Predict the change, if any, due to the following perturbations in the table, and determine whether the equilibrium shifts to the right or to the left. | Perturbation | Change in Composition | Shift in Equilibrium | |---------------------------------------|-----------------------|----------------------| | Some \(\text{H}_2\text{O}\) is removed. | ? | ☐ to the right ☐ to the left ☐ (none) | | The pressure of \(\text{O}_2\) will: | ? | ☐ to the right ☐ to the left ☐ (none) | | Some \(\text{O}_2\) is added. | ? | ☐ to the right ☐ to the left ☐ (none) | | The pressure of \(\text{CO}_2\) will: | ? | ☐ to the right ☐ to the left ☐ (none) | **Explanation & Discussion:** Use Le Chatelier's Principle to evaluate how the system responds to each change. For example, removing \(\text{H}_2\text{O}\) might shift the equilibrium towards the products to restore balance, while adding \(\text{O}_2\) could push the equilibrium to the right to consume the excess reactants. **Action:** - Review each scenario. - Predict and check your answers using the principles of chemical equilibrium. **Note:** This is a hypothetical exercise to aid in understanding equilibrium responses in chemical reactions.
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