acetone/ water HỌ H Na O :CI:6 Select to Add Arrows acetone/ water ci H To acetone/water < CI-H F Please select a drawing or reagent from the question area.
acetone/ water HỌ H Na O :CI:6 Select to Add Arrows acetone/ water ci H To acetone/water < CI-H F Please select a drawing or reagent from the question area.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic steps.
Be sure to account for all bond-breaking and bond-making steps.
---
The image includes:
1. **Top Structure: Reactant**
- A benzene ring attached to a propyl group (3-carbon chain).
- A sodium cation (Na⁺) and an alcohol group (OH) on the third carbon.
- Label: "Select to Add Arrows"
2. **Reaction Conditions**
- Arrow indicating the use of acetone and water as solvents.
3. **Bottom Structure: Product**
- The product features a benzene ring.
- The propyl group appears to have undergone a stereochemical change, shown by dashed and wedged bonds.
- There is a chloride ion (Cl⁻) depicted as leaving.
**Instructions for Education:**
Students are expected to correctly place curved arrows to depict the electron flow that accounts for the mechanistic transformation from reactant to product, ensuring all bond transformations are annotated clearly.

Transcribed Image Text:The image presents a chemical reaction where acetone/water is used as the solvent.
1. **Reactants:**
- A benzene ring attached to a carbon chain (presumably a phenyl group) is shown reacting with a chlorine atom (Cl) connected to another carbon with hydrogens.
2. **Reaction Pathway:**
- The first part of the diagram shows the reactants transformed (inside a dotted box labeled "Select to Add Arrows") into a sodium ion (Na⁺) and an alkoxide ion (an oxygen atom single-bonded to a carbon, double-bonded to another oxygen, and with a negative charge), along with H and Cl atoms.
3. **Products:**
- Two possible products are depicted. Both involve the initial phenyl group, with a chiral carbon connected to a chlorine atom and a hydrogen atom. The configuration of the chiral center differs in each product ("wedge" and "dash" indicating 3D spatial orientation).
4. **Note:**
- The notation "Select to Add Arrows" suggests that intermediates or transition states might be added to fully describe the reaction mechanism.
Overall, this diagram illustrates a substitution reaction where solvent effects (acetone/water) influence the formation of stereoisomers from a chiral compound.
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