a,B-Unsaturated aldehydes and ketones can undergo reaction with nucleophiles at the B carbon, as shown below. + :Nu-H Nu H a. Draw a resonance form for the unsaturated carbonyl that accounts for this reactivity. b. This reaction is called reaction. a 1,2-conjugate addition. an electrophilic addition. a direct addition a 1,2-addition. a. b. С. d.
a,B-Unsaturated aldehydes and ketones can undergo reaction with nucleophiles at the B carbon, as shown below. + :Nu-H Nu H a. Draw a resonance form for the unsaturated carbonyl that accounts for this reactivity. b. This reaction is called reaction. a 1,2-conjugate addition. an electrophilic addition. a direct addition a 1,2-addition. a. b. С. d.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:3.
a,B-Unsaturated aldehydes and ketones can undergo reaction with nucleophiles at the B carbon, as
shown below.
||
+ :Nu-H
Nu
H
a. Draw a resonance form for the unsaturated carbonyl that accounts for this reactivity.
b. This reaction is called
reaction.
a 1,2-conjugate addition.
an electrophilic addition.
а.
b.
С.
a direct addition
d.
a 1,2-addition.
Transcribed Image Text:5.
Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all
relevant stereochemistry.
CH3
HNO3
H2/Pt
H2SO,
ethanol
a.
(CH;CO)20
Br2
H2N-
-CH3
pyridine
FeBr3
b.
NaN3
1. LIAIH4, ether,
Br
2. Но
С.
||
CH3CC1
AIC13
NAOH
NHCCH3
H20
d.
NH2
H2/Ni
е.
1. LIAIH4, THE
2. Но
NH2
f.
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