a,B-Unsaturated aldehydes and ketones can undergo reaction with nucleophiles at the B carbon, as shown below. + :Nu-H Nu H a. Draw a resonance form for the unsaturated carbonyl that accounts for this reactivity. b. This reaction is called reaction. a 1,2-conjugate addition. an electrophilic addition. a direct addition a 1,2-addition. a. b. С. d.

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3.
a,B-Unsaturated aldehydes and ketones can undergo reaction with nucleophiles at the B carbon, as
shown below.
||
+ :Nu-H
Nu
H
a. Draw a resonance form for the unsaturated carbonyl that accounts for this reactivity.
b. This reaction is called
reaction.
a 1,2-conjugate addition.
an electrophilic addition.
а.
b.
С.
a direct addition
d.
a 1,2-addition.
Transcribed Image Text:3. a,B-Unsaturated aldehydes and ketones can undergo reaction with nucleophiles at the B carbon, as shown below. || + :Nu-H Nu H a. Draw a resonance form for the unsaturated carbonyl that accounts for this reactivity. b. This reaction is called reaction. a 1,2-conjugate addition. an electrophilic addition. а. b. С. a direct addition d. a 1,2-addition.
5.
Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all
relevant stereochemistry.
CH3
HNO3
H2/Pt
H2SO,
ethanol
a.
(CH;CO)20
Br2
H2N-
-CH3
pyridine
FeBr3
b.
NaN3
1. LIAIH4, ether,
Br
2. Но
С.
||
CH3CC1
AIC13
NAOH
NHCCH3
H20
d.
NH2
H2/Ni
е.
1. LIAIH4, THE
2. Но
NH2
f.
Transcribed Image Text:5. Give the major organic product(s) of each of the following reactions or sequences of reactions. Show all relevant stereochemistry. CH3 HNO3 H2/Pt H2SO, ethanol a. (CH;CO)20 Br2 H2N- -CH3 pyridine FeBr3 b. NaN3 1. LIAIH4, ether, Br 2. Но С. || CH3CC1 AIC13 NAOH NHCCH3 H20 d. NH2 H2/Ni е. 1. LIAIH4, THE 2. Но NH2 f.
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