a.) Would you expect this reaction to take place in a single step? Why or why not? b.) This reaction is thought to take place by means of the following mechanism: Step 1: HBr + O2 HOOBI (slow) Step 2: HBr + HOOBr 2 HOBr (fast) Step 3: 2 HBr + 2 HOBT 2 H20 + 2 Br2 (fast) i. Identify the two intermediates. ii. Which step has the greatest activation energy? ii. How many "peaks" will the potential energy diagram for the reaction mechanism have? iv. Which step is called the rate determining step in this mechanism?
a.) Would you expect this reaction to take place in a single step? Why or why not? b.) This reaction is thought to take place by means of the following mechanism: Step 1: HBr + O2 HOOBI (slow) Step 2: HBr + HOOBr 2 HOBr (fast) Step 3: 2 HBr + 2 HOBT 2 H20 + 2 Br2 (fast) i. Identify the two intermediates. ii. Which step has the greatest activation energy? ii. How many "peaks" will the potential energy diagram for the reaction mechanism have? iv. Which step is called the rate determining step in this mechanism?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Given the reaction: 4 HBr+ 02 2 H20+2 Br
a.) Would you expect this reaction to take place in a single step? Why or why not?
b.) This reaction is thought to take place by means of the following mechanism:
Step 1: HBr + O2 HOOBR (slow)
Step 2: HBr + HQOBr 2 HOBI (fast)
Step 3: 2 HBr +2 HOBr 2 H2O + 2 Br2 (fast)
i. Identify the two intermediates.
ii. Which step has the greatest activation energy?
ii. How many "peaks" will the potential energy diagram for the reaction
mechanism have?
iv. Which step is called the rate determining step in this mechanism?
v. In order to have successful collisions, the colliding particles must have
both the proper amount of energy and the proper
(fill in blank)?
vi. On the set of axes below, draw the shape of the curve you might
expect for the reaction in this question. The overall reaction is
exothermic.
Enthalpy
Progress of Reaction
c.) A catalyst is discovered which increases the rate of Step 3. How will this affect the
rate of the overall reaction? Explain your answer.
d.) A catalyst is discovered which increases the rate of Step 1. How will this affect the
rate of the overall reaction? Explain your answer.
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