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a. Propose a mechanism. b. Predict the signals you would expect to see in a 'H – NMR spectrum of malate.

a. Propose a mechanism. b. Predict the signals you would expect to see in a 'H – NMR spectrum of malate.

Biochemistry
Biochemistry
9th Edition
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
Section: Chapter Questions
Problem 1P
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P12.8: The reaction below, catalyzed by the enzyme malate synthase, is part of the glyoxylate cycle of plants and some bacteria. It is the glyoxylate cycle that allows these organisms to convert acetyl CoA, derived from the metabolism of oils, into glucose. acetyl-CoA H20 COASH OH H. glyoxylate malate a. Propose a mechanism. b. Predict the signals you would expect to see in a 'H – NMR spectrum of malate.
Transcribed Image Text:P12.8: The reaction below, catalyzed by the enzyme malate synthase, is part of the glyoxylate cycle of plants and some bacteria. It is the glyoxylate cycle that allows these organisms to convert acetyl CoA, derived from the metabolism of oils, into glucose. acetyl-CoA H20 COASH OH H. glyoxylate malate a. Propose a mechanism. b. Predict the signals you would expect to see in a 'H – NMR spectrum of malate.
Expert Solution
Step 1

Malate synthase converts glyoxylate to malate by combining with acetyl CoA. The malate formed can enter citric acid cycle.

The glyoxylate cycle is a cyclic process that converts two carbon fragment acetyl CoA to four-carbon compound succinate.

The glyoxylate cycle occurs in glyoxysomes.

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