Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Thermochemistry and Reaction Enthalpy Calculations**
This section covers the standard enthalpy of formation (\( \Delta H_f^\circ \)) values for various substances, which are essential for calculating reaction enthalpies.
**Table: Standard Enthalpy of Formation (\( \Delta H_f^\circ \))**
| Substance and State | \( \Delta H_f^\circ \) (kJ/mol) |
|-----------------------|------------------------|
| Ca\(_3\)(PO\(_4\))\(_2\) (s) | –4126 |
| CaSO\(_4\) (s) | –1433 |
| CH\(_4\) (g) | –75 |
| HCN (g) | 135.1 |
| HCl (g) | –92 |
| H\(_2\)O (g) | –242 |
| NH\(_3\) (g) | –46 |
| NH\(_4\)Cl (s) | –314 |
| O\(_2\) (g) | 0 |
| H\(_3\)PO\(_4\) (l) | –1267 |
| H\(_2\)SO\(_4\) (l) | –814 |
**Reactions and Molecular Models**
_a._ Reaction pathway illustrated by molecular models:
The reaction involves gaseous molecules depicted with color-coded atoms:
- Nitrogen (N),
- Hydrogen (H),
- Oxygen (O),
- Carbon (C).
The diagram shows reactant molecules combining to form product molecules in a visual representation. The enthalpy change (\( \Delta H^\circ \)) for this reaction needs to be calculated.
\[ \Delta H^\circ = \_\_\_\_ \text{ kJ} \]
_b._ Reaction Equation:
\[ \text{Ca}_3(\text{PO}_4)_2(s) + 3\text{H}_2\text{SO}_4(l) \rightarrow 3\text{CaSO}_4(s) + 2\text{H}_3\text{PO}_4(l) \]
\[ \Delta H^\circ = \_\_\_\_ \text{ kJ} \]
_c._ Reaction Equation:
\[ \text{NH}_3(g](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ffa82188d-7c1b-4aa7-8add-9da07b86f459%2F48a33fd8-bc04-4d30-8998-fa70950e8c11%2F4erf1l_processed.png&w=3840&q=75)
Transcribed Image Text:**Thermochemistry and Reaction Enthalpy Calculations**
This section covers the standard enthalpy of formation (\( \Delta H_f^\circ \)) values for various substances, which are essential for calculating reaction enthalpies.
**Table: Standard Enthalpy of Formation (\( \Delta H_f^\circ \))**
| Substance and State | \( \Delta H_f^\circ \) (kJ/mol) |
|-----------------------|------------------------|
| Ca\(_3\)(PO\(_4\))\(_2\) (s) | –4126 |
| CaSO\(_4\) (s) | –1433 |
| CH\(_4\) (g) | –75 |
| HCN (g) | 135.1 |
| HCl (g) | –92 |
| H\(_2\)O (g) | –242 |
| NH\(_3\) (g) | –46 |
| NH\(_4\)Cl (s) | –314 |
| O\(_2\) (g) | 0 |
| H\(_3\)PO\(_4\) (l) | –1267 |
| H\(_2\)SO\(_4\) (l) | –814 |
**Reactions and Molecular Models**
_a._ Reaction pathway illustrated by molecular models:
The reaction involves gaseous molecules depicted with color-coded atoms:
- Nitrogen (N),
- Hydrogen (H),
- Oxygen (O),
- Carbon (C).
The diagram shows reactant molecules combining to form product molecules in a visual representation. The enthalpy change (\( \Delta H^\circ \)) for this reaction needs to be calculated.
\[ \Delta H^\circ = \_\_\_\_ \text{ kJ} \]
_b._ Reaction Equation:
\[ \text{Ca}_3(\text{PO}_4)_2(s) + 3\text{H}_2\text{SO}_4(l) \rightarrow 3\text{CaSO}_4(s) + 2\text{H}_3\text{PO}_4(l) \]
\[ \Delta H^\circ = \_\_\_\_ \text{ kJ} \]
_c._ Reaction Equation:
\[ \text{NH}_3(g
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