Given the following data 2 CIF (g) + O₂(g) → Cl₂ O(g) + F₂O(g) 2 CIF3 (9) +202(g) → Cl₂ O(g) + 3F₂O(g) 2F2(g) + O₂(g) →2F₂O(g) calculate A H for the reaction AH= CIF (g) + F₂ (g) → CIF3 (9) kj AH 167.4 kJ Δ Η = 341.4 kJ AH-43.4 kJ

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**Experimental Calculation of Enthalpy Change Using a Coffee-Cup Calorimeter**

In a coffee-cup calorimeter experiment, 110.0 mL of 1.2 M NaOH and 110.0 mL of 1.2 M HCl are mixed. Both solutions were initially at a temperature of 22.5°C. After the reaction occurs, the final temperature recorded is 30.5°C. 

Assumptions for calculations:
- The density of the solutions is 1.0 g/cm³.
- The specific heat capacity of the solutions is 4.18 J/°C·g.
- No heat is lost to the surroundings or the calorimeter.

### Objective:
Calculate the enthalpy change (ΔH) for the neutralization reaction of HCl by NaOH.

### Given Data:
- Volume of NaOH solution: 110.0 mL
- Volume of HCl solution: 110.0 mL
- Molarity of NaOH: 1.2 M
- Molarity of HCl: 1.2 M
- Initial temperature: 22.5°C
- Final temperature: 30.5°C
- Density of solutions: 1.0 g/cm³
- Specific heat capacity: 4.18 J/°C·g

### Results:
The enthalpy change (ΔH) is calculated to be 0.182 kJ/mol.

This example demonstrates an essential calorimetry technique to determine the energy change in a chemical reaction, providing a hands-on approach to understanding thermodynamics in solutions.
Transcribed Image Text:**Experimental Calculation of Enthalpy Change Using a Coffee-Cup Calorimeter** In a coffee-cup calorimeter experiment, 110.0 mL of 1.2 M NaOH and 110.0 mL of 1.2 M HCl are mixed. Both solutions were initially at a temperature of 22.5°C. After the reaction occurs, the final temperature recorded is 30.5°C. Assumptions for calculations: - The density of the solutions is 1.0 g/cm³. - The specific heat capacity of the solutions is 4.18 J/°C·g. - No heat is lost to the surroundings or the calorimeter. ### Objective: Calculate the enthalpy change (ΔH) for the neutralization reaction of HCl by NaOH. ### Given Data: - Volume of NaOH solution: 110.0 mL - Volume of HCl solution: 110.0 mL - Molarity of NaOH: 1.2 M - Molarity of HCl: 1.2 M - Initial temperature: 22.5°C - Final temperature: 30.5°C - Density of solutions: 1.0 g/cm³ - Specific heat capacity: 4.18 J/°C·g ### Results: The enthalpy change (ΔH) is calculated to be 0.182 kJ/mol. This example demonstrates an essential calorimetry technique to determine the energy change in a chemical reaction, providing a hands-on approach to understanding thermodynamics in solutions.
### Given the following data

1. \(2 \text{ClF}(g) + O_2(g) \rightarrow \text{Cl}_2O(g) + \text{F}_2O(g)\) 
   \(\quad \Delta H = 167.4 \, \text{kJ}\)

2. \(2 \text{ClF}_3(g) + 2 O_2(g) \rightarrow \text{Cl}_2O(g) + 3\text{F}_2O(g)\) 
   \(\quad \Delta H = 341.4 \, \text{kJ}\)

3. \(2 \text{F}_2(g) + O_2(g) \rightarrow 2 \text{F}_2O(g)\) 
   \(\quad \Delta H = -43.4 \, \text{kJ}\)

### Calculate \(\Delta H\) for the reaction

\(\text{ClF}(g) + \text{F}_2(g) \rightarrow \text{ClF}_3(g)\)

\[
\Delta H = \_\_\_\_\_ \, \text{kJ}
\]

### Explanation

- **Equation 1:** Describes the reaction where 2 moles of chlorine monofluoride (ClF) react with oxygen (O2) to form chlorine monoxide (Cl2O) and fluoro monoxide (F2O) with an enthalpy change (\(\Delta H\)) of 167.4 kJ.

- **Equation 2:** Describes the reaction where 2 moles of chlorine trifluoride (ClF3) react with 2 moles of oxygen (O2) to form chlorine monoxide (Cl2O) and 3 moles of fluoro monoxide (F2O) with an enthalpy change (\(\Delta H\)) of 341.4 kJ.

- **Equation 3:** Describes the reaction where 2 moles of difluorine (F2) react with oxygen (O2) to form 2 moles of fluoro monoxide (F2O) with an enthalpy change (\(\Delta H\)) of -43.4 kJ.

You are tasked with calculating the enthalpy change (\(\Delta H\)) for the reaction where chlorine monofluoride (ClF) reacts with dif
Transcribed Image Text:### Given the following data 1. \(2 \text{ClF}(g) + O_2(g) \rightarrow \text{Cl}_2O(g) + \text{F}_2O(g)\) \(\quad \Delta H = 167.4 \, \text{kJ}\) 2. \(2 \text{ClF}_3(g) + 2 O_2(g) \rightarrow \text{Cl}_2O(g) + 3\text{F}_2O(g)\) \(\quad \Delta H = 341.4 \, \text{kJ}\) 3. \(2 \text{F}_2(g) + O_2(g) \rightarrow 2 \text{F}_2O(g)\) \(\quad \Delta H = -43.4 \, \text{kJ}\) ### Calculate \(\Delta H\) for the reaction \(\text{ClF}(g) + \text{F}_2(g) \rightarrow \text{ClF}_3(g)\) \[ \Delta H = \_\_\_\_\_ \, \text{kJ} \] ### Explanation - **Equation 1:** Describes the reaction where 2 moles of chlorine monofluoride (ClF) react with oxygen (O2) to form chlorine monoxide (Cl2O) and fluoro monoxide (F2O) with an enthalpy change (\(\Delta H\)) of 167.4 kJ. - **Equation 2:** Describes the reaction where 2 moles of chlorine trifluoride (ClF3) react with 2 moles of oxygen (O2) to form chlorine monoxide (Cl2O) and 3 moles of fluoro monoxide (F2O) with an enthalpy change (\(\Delta H\)) of 341.4 kJ. - **Equation 3:** Describes the reaction where 2 moles of difluorine (F2) react with oxygen (O2) to form 2 moles of fluoro monoxide (F2O) with an enthalpy change (\(\Delta H\)) of -43.4 kJ. You are tasked with calculating the enthalpy change (\(\Delta H\)) for the reaction where chlorine monofluoride (ClF) reacts with dif
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