A. For the following reaction, give a full curved-arrow pushing mechanism for formation of BOTH products and indicate the Lewis acid and base at each step (LA or LB) and whether they are also Bronsted acids and bases (BA or BB). Include all reasonable resonance contributors for any intermediates AND INDICATE THE MAJOR RESONANCE CONTRIBUTOR IF APPROPRIATE B. Indicate which product, A or B, would be formed under thermodynamically controlled conditions and which would be formed under kinetically controlled conditions and give a BRIEF explanation of the role of temperature in determining kinetic and thermodynamic control C. Draw a reaction energy diagram for both reactions on the same diagram.

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Chapter1: Chemical Foundations
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explanation of the role
of temperature in determining kinetic and
thermodynamic control
C. Draw a reaction energy diagram for both
reactions on the same diagram.
To preview the image Click Here +
energy
Br
CH3OH
LOCH3
heat
+
H3CO
A
B
reaction coordinate
Transcribed Image Text:explanation of the role of temperature in determining kinetic and thermodynamic control C. Draw a reaction energy diagram for both reactions on the same diagram. To preview the image Click Here + energy Br CH3OH LOCH3 heat + H3CO A B reaction coordinate
A. For the following reaction, give a full curved-arrow
pushing mechanism for formation of BOTH
products and indicate the Lewis acid and base at
each step (LA or LB) and whether they are also
Bronsted acids and bases (BA or BB). Include all
reasonable resonance contributors for any
intermediates AND INDICATE THE MAJOR
RESONANCE CONTRIBUTOR IF APPROPRIATE
B. Indicate which product, A or B, would be formed
under thermodynamically controlled conditions and
which would be formed under kinetically controlled
conditions and give a BRIEF explanation of the role
of temperature in determining kinetic and
thermodynamic control
C. Draw a reaction energy diagram for both
reactions on the same diagram.
Transcribed Image Text:A. For the following reaction, give a full curved-arrow pushing mechanism for formation of BOTH products and indicate the Lewis acid and base at each step (LA or LB) and whether they are also Bronsted acids and bases (BA or BB). Include all reasonable resonance contributors for any intermediates AND INDICATE THE MAJOR RESONANCE CONTRIBUTOR IF APPROPRIATE B. Indicate which product, A or B, would be formed under thermodynamically controlled conditions and which would be formed under kinetically controlled conditions and give a BRIEF explanation of the role of temperature in determining kinetic and thermodynamic control C. Draw a reaction energy diagram for both reactions on the same diagram.
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