A. For the following reaction, give a full curved-arrow pushing mechanism for formation of BOTH products and indicate the Lewis acid and base at each step (LA or LB) and whether they are also Bronsted acids and bases (BA or BB). Include all reasonable resonance contributors for any intermediates AND INDICATE THE MAJOR RESONANCE CONTRIBUTOR IF APPROPRIATE B. Indicate which product, A or B, would be formed under thermodynamically controlled conditions and which would be formed under kinetically controlled conditions and give a BRIEF explanation of the role of temperature in determining kinetic and thermodynamic control C. Draw a reaction energy diagram for both reactions on the same diagram.
A. For the following reaction, give a full curved-arrow pushing mechanism for formation of BOTH products and indicate the Lewis acid and base at each step (LA or LB) and whether they are also Bronsted acids and bases (BA or BB). Include all reasonable resonance contributors for any intermediates AND INDICATE THE MAJOR RESONANCE CONTRIBUTOR IF APPROPRIATE B. Indicate which product, A or B, would be formed under thermodynamically controlled conditions and which would be formed under kinetically controlled conditions and give a BRIEF explanation of the role of temperature in determining kinetic and thermodynamic control C. Draw a reaction energy diagram for both reactions on the same diagram.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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