Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
What hydrogen atoms in each compound have a pKa ≤ 25?
Expert Solution
Step 1
The pKa of alpha hydrogens attached to carbonyl compounds is below 25. The negative charge of the anion formed after removing the proton is stabilized by delocalization of electrons onto the electronegative atom, that is oxygen. The highlighted hydrogens shown have pKa less than or equal to 25.
Step 2
The pKa of alpha hydrogens attached to carbonyl compounds is below 25. The negative charge of the anion formed after removing the proton is stabilized by delocalization of electrons onto the electronegative atom, that is oxygen. The highlighted hydrogens shown have pKa less than or equal to 25.
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