A system constant external pressu undergoes an increase in volume. What is the effect on the surroundings? O Energy is transferred as pressure-volume work done by the surroundings on the system. O None of the above. O Energy is transferred as heat from the system to the undings
A system constant external pressu undergoes an increase in volume. What is the effect on the surroundings? O Energy is transferred as pressure-volume work done by the surroundings on the system. O None of the above. O Energy is transferred as heat from the system to the undings
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:**Understanding Pressure-Volume Work in Thermodynamic Systems**
**Question:**
A system under constant external pressure undergoes an increase in volume. What is the effect on the surroundings?
**Options:**
1. **Energy is transferred as pressure-volume work done by the surroundings on the system.** (This option is selected)
2. None of the above.
3. Energy is transferred as heat from the system to the surroundings.
4. Energy is transferred as heat from the surroundings to the system.
5. Energy is transferred as pressure-volume work done on the surroundings.
**Explanation:**
When a system is subjected to constant external pressure and there is an increase in the volume of the system, the process can be described using the principles of thermodynamics.
In such a scenario, energy in the form of work is transferred. The key consideration here is whether the work is being done on the system or by the system and what effect this has on the surroundings.
- **Pressure-Volume Work in Thermodynamics:**
- When the volume of the system increases under constant pressure, work is done by the system on the surroundings. This results in the system transferring energy to its surroundings.
- This process can be represented by the equation \( W = P \Delta V \), where \( W \) is the work done by the system, \( P \) is the constant external pressure, and \( \Delta V \) is the change in volume.
The correct interpretation given the options provided is:
**Option 5: Energy is transferred as pressure-volume work done on the surroundings.**
This indicates that as the system expands, it performs work on its surroundings by transferring energy in line with the principles of thermodynamics.
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