A solution of sodium chlorite is prepared using 0.38 mol L1 NaOH as the solvent. The pK, of chlorous acid is 2. The concentration of sodium chlorite after mixing, before any reaction takes place is 0.24 mol L1. Calculate the equilibrium concentrations of all acid species: [ HCIO2 ], [ CIO2 ], the pH and the pOH in the solution. Some assumptions may not work, on the other hand, if you do not make the correc assumptions first, the quadratic formula will give you the wrong answer. [ HCIO2 ) mol L'1, [ CIO2 ) - mol L1, pH = pOH

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter16: Principles Of Chemical Reactivity: The Chemistry Of Acids And Bases
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Problem 108GQ: The hydrogen phthalate ion, C8HsO4, is a weak acid with Ka = 3.91 106....
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A solution of sodium chlorite is prepared using 0.38 mol L1 NaOH as the solvent. The pK, of chlorous
acid is 2. The concentration of sodium chlorite after mixing, before any reaction takes place is 0.24 mol
L1. Calculate the equilibrium concentrations of all acid species: [ HCIO2 ), [ CIO2 1, the pH and the
pOH in the solution. Some assumptions may not work, on the other hand, if you do not make the correct
assumptions first, the quadratic formula will give you the wrong answer.
[ HCIO2 ] -
mol L1,
[ CIO2 ] =
mol L-1,
pH =
pOH
Transcribed Image Text:A solution of sodium chlorite is prepared using 0.38 mol L1 NaOH as the solvent. The pK, of chlorous acid is 2. The concentration of sodium chlorite after mixing, before any reaction takes place is 0.24 mol L1. Calculate the equilibrium concentrations of all acid species: [ HCIO2 ), [ CIO2 1, the pH and the pOH in the solution. Some assumptions may not work, on the other hand, if you do not make the correct assumptions first, the quadratic formula will give you the wrong answer. [ HCIO2 ] - mol L1, [ CIO2 ] = mol L-1, pH = pOH
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