A solution of HCIO4 was standardized by dissolving 0.4008 g of primary-standard-grade HgO in a solution of KBr: HgO(s) + 4Br + H2O → Hg Br42- + 20H The liberated OH consumed 43.58 mL of the acid. Calculate the molar concentration of the HC104. Concentration = M
A solution of HCIO4 was standardized by dissolving 0.4008 g of primary-standard-grade HgO in a solution of KBr: HgO(s) + 4Br + H2O → Hg Br42- + 20H The liberated OH consumed 43.58 mL of the acid. Calculate the molar concentration of the HC104. Concentration = M
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Educational Content: Standardization of an HClO₄ Solution**
In the experiment, a solution of perchloric acid (\( \text{HClO}_4 \)) was standardized. This process involved dissolving 0.4008 grams of primary-standard-grade mercuric oxide (\( \text{HgO} \)) in a solution of potassium bromide (\( \text{KBr} \)). The chemical reaction that occurs is as follows:
\[ \text{HgO(s)} + 4\text{Br}^- + \text{H}_2\text{O} \rightarrow \text{HgBr}_4^{2-} + 2\text{OH}^- \]
During the reaction, hydroxide ions (\( \text{OH}^- \)) are liberated. These hydroxide ions were neutralized by 43.58 mL of the perchloric acid solution. The task is to calculate the molar concentration of the \( \text{HClO}_4 \) used.
**Calculation Required for Concentration:**
The concentration of \( \text{HClO}_4 \) (in molarity, M) needs to be calculated based on the data and reaction provided.
**Concentration = \_\_\_\_\_\_ M**
> Make sure to follow the appropriate stoichiometric calculations as a part of the standardization process to determine the molarity of the \( \text{HClO}_4 \) solution accurately.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F2bafa3d4-8362-4eaf-b0f1-0c492e72839c%2F714f71a4-2c97-4911-97e2-4688ab4570f5%2F1r8ddgo_processed.png&w=3840&q=75)
Transcribed Image Text:**Educational Content: Standardization of an HClO₄ Solution**
In the experiment, a solution of perchloric acid (\( \text{HClO}_4 \)) was standardized. This process involved dissolving 0.4008 grams of primary-standard-grade mercuric oxide (\( \text{HgO} \)) in a solution of potassium bromide (\( \text{KBr} \)). The chemical reaction that occurs is as follows:
\[ \text{HgO(s)} + 4\text{Br}^- + \text{H}_2\text{O} \rightarrow \text{HgBr}_4^{2-} + 2\text{OH}^- \]
During the reaction, hydroxide ions (\( \text{OH}^- \)) are liberated. These hydroxide ions were neutralized by 43.58 mL of the perchloric acid solution. The task is to calculate the molar concentration of the \( \text{HClO}_4 \) used.
**Calculation Required for Concentration:**
The concentration of \( \text{HClO}_4 \) (in molarity, M) needs to be calculated based on the data and reaction provided.
**Concentration = \_\_\_\_\_\_ M**
> Make sure to follow the appropriate stoichiometric calculations as a part of the standardization process to determine the molarity of the \( \text{HClO}_4 \) solution accurately.
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