A solution is made by dissolving 0.732 mol0.732 mol of nonelectrolyte solute in 871 g871 g of benzene. Calculate the freezing point, ?f,Tf, and boiling point, ?b,Tb, of the solution. Constants can be found in the table of colligative constants. Solvent Formula K f value* (°C/ m ) Normal freezing point ( °C)   K b value (°C/ m ) Normal boiling point ( °C)  water  H 2 O  1.86  0.00  0.512  100.00  benzene  C 6 H 6  5.12  5.49  2.53  80.1  cyclohexane  C 6 H 12  20.8  6.59  2.92  80.7  ethanol  C 2 H 6 O  1.99 –117.3  1.22  78.4  carbon  tetrachloride   CCl 4  29.8  –22.9  5.03  76.8

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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A solution is made by dissolving 0.732 mol0.732 mol of nonelectrolyte solute in 871 g871 g of benzene. Calculate the freezing point, ?f,Tf, and boiling point, ?b,Tb, of the solution. Constants can be found in the table of colligative constants.

Solvent

Formula

K f value*

(°C/ m )

Normal freezing

point ( °C)

  K b value

(°C/ m )

Normal boiling

point ( °C)

 water

 H 2 O

 1.86

 0.00

 0.512

 100.00

 benzene

 C 6 H 6

 5.12

 5.49

 2.53

 80.1

 cyclohexane

 C 6 H 12

 20.8

 6.59

 2.92

 80.7

 ethanol

 C 2 H 6 O

 1.99

–117.3

 1.22

 78.4

 carbon
 tetrachloride 

 CCl 4

 29.8

 –22.9

 5.03

 76.8

 camphor 

 C 10 H 16 O

 37.8

 176

 

 

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