A sample of 5.034 g containing ammonium sulphate was warmed with 50 cm³ of 0.400 M NaOH (excess). After the evolution of ammonia had ceased, the excess of NaOH was back titrated against HCI, requiring 33.0 cm³ of 0.1100 M acid. Calculate the mass (in grams) of ammonium sulphate in the original sample. (NH4)2SO4 + 2NaOH → Na₂(SO4) + 2H₂O + 2NH3 Note: RAM's: 0:15.999 H: 1.008 N:14.007 S: 32.066

Chemistry: Principles and Reactions
8th Edition
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Author:William L. Masterton, Cecile N. Hurley
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Chapter14: Equilibria In Acid-base Solutions
Section: Chapter Questions
Problem 33QAP: A buffer is prepared in which the ratio [ H2PO4 ]/[ HPO42 ]is 3.0. (a) What is the pH of this...
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Answer ALL parts:
(a)
A sample of 5.034 g containing ammonium sulphate was warmed
with 50 cm³ of 0.400 M NaOH (excess). After the evolution of
ammonia had ceased, the excess of NaOH was back titrated
against HCI, requiring 33.0 cm³ of 0.1100 M acid. Calculate the
mass (in grams) of ammonium sulphate in the original sample.
(NH4)2SO4 + 2NaOH → Na₂(SO4) + 2H₂O + 2NH3
Note: RAM's: 0:15.999 H: 1.008 N:14.007
(b)
Calculate the pH of each of the following solutions and report your
answer to three decimal places:
(a) 0.012 mol dm³ H₂SO4
(b) 5.000 x 10 mol dm³ NaOH
NOTE: Kw = 10 14
S: 32.066
D
(c)
A weak solution of ammonia (pKb: 4.767, 0.06 mol dm³, 20 cm³) is
titrated against 0.03 mol dm³ HCI. Calculate:
(i) pH at 0.00 cm³ HCI added
(ii) pH at 12 cm³ HCI added
(iii) pH at equivalence point
Transcribed Image Text:Answer ALL parts: (a) A sample of 5.034 g containing ammonium sulphate was warmed with 50 cm³ of 0.400 M NaOH (excess). After the evolution of ammonia had ceased, the excess of NaOH was back titrated against HCI, requiring 33.0 cm³ of 0.1100 M acid. Calculate the mass (in grams) of ammonium sulphate in the original sample. (NH4)2SO4 + 2NaOH → Na₂(SO4) + 2H₂O + 2NH3 Note: RAM's: 0:15.999 H: 1.008 N:14.007 (b) Calculate the pH of each of the following solutions and report your answer to three decimal places: (a) 0.012 mol dm³ H₂SO4 (b) 5.000 x 10 mol dm³ NaOH NOTE: Kw = 10 14 S: 32.066 D (c) A weak solution of ammonia (pKb: 4.767, 0.06 mol dm³, 20 cm³) is titrated against 0.03 mol dm³ HCI. Calculate: (i) pH at 0.00 cm³ HCI added (ii) pH at 12 cm³ HCI added (iii) pH at equivalence point
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