A proposed mechanism for the Br-catalyzed aqueous reaction is shown below. Br H* + HNO, + CHẠNH, CH₂N₂ + 2H₂O H+ + HNO₂H₂NO rapid equilib. slow H₂NO₂ + Br¯ONBr + H₂O ONBr + CH,NH, * CHẠN} + H,O + Br fast Apply steady-state approximiation to answer the following questions. Write the letter of your answer. What is the rate of the intermediates? A.0 B. 1 Which of the following corresponds to the rate of ONBr? A.K. [H₂NO₂+] k BK₂-[H₂NO₂+][Br] C.k[ONB][CH₂NH₂] Given the following expression for the rate of H₂NO₂*, what is the rate constant for each term? X[H+][HNO₂]-Y[H₂NO₂+]-Z[H₂NO₂+][Br] Use the following choices. A. K₁ B.K.1 C. K2 D.K3 X= Y=

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Question 5
A proposed mechanism for the Br-catalyzed aqueous reaction is shown below.
Br
H+ + HNO₂ + C6H5NH₂
CH,N₂ + 2H₂O
k₂
H+ + HNO₂ H₂NO
rapid equilib.
slow
H₂NO+ Br¯ONBr + H₂O
fast
ONBr + CH₂NH₂CH₂N₂ + H₂O + Br¯
Apply steady-state approximiation to answer the following questions. Write the letter of your answer.
What is the rate of the intermediates?
A. 0
B. 1
Which of the following corresponds to the rate of ONBr?
A.k. [H₂NO₂+]
B.k₂=[H₂NO₂+][Br-]
C.k[ONBr][CH₂NH₂]
Given the following expression for the rate of H₂NO₂*, what is the rate constant for each term?
X[H+][HNO₂]-Y[H₂NO₂+]-Z[H₂NO₂+][Br]
Use the following choices.
A. K₁
B.K.1
C. K2
D. k3
X =
Y =
Z=
Transcribed Image Text:Question 5 A proposed mechanism for the Br-catalyzed aqueous reaction is shown below. Br H+ + HNO₂ + C6H5NH₂ CH,N₂ + 2H₂O k₂ H+ + HNO₂ H₂NO rapid equilib. slow H₂NO+ Br¯ONBr + H₂O fast ONBr + CH₂NH₂CH₂N₂ + H₂O + Br¯ Apply steady-state approximiation to answer the following questions. Write the letter of your answer. What is the rate of the intermediates? A. 0 B. 1 Which of the following corresponds to the rate of ONBr? A.k. [H₂NO₂+] B.k₂=[H₂NO₂+][Br-] C.k[ONBr][CH₂NH₂] Given the following expression for the rate of H₂NO₂*, what is the rate constant for each term? X[H+][HNO₂]-Y[H₂NO₂+]-Z[H₂NO₂+][Br] Use the following choices. A. K₁ B.K.1 C. K2 D. k3 X = Y = Z=
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