a) [Ni(en)2(NO2)2] b) [Ni(N,N'-dmen)2(NO2)2] c) [Ni(N,N-dmen)2(ONO)2] Rank the compounds in terms of stability and Explain why?

Q: The d-electron count of the transition metal center for [(7-CSHS)Ir(CO)2(CH3)* and [Rh(PPH3)3Cl],…

A: Calculate metal electrons in organometallic compound [η5-C5H5IrCO2CH3]+ and  RhPPh33Cl Given: Atomic…

Q: List the cobalt complexes in order of increasing Kstab values. Using one of the cobalt(II) complexes…

A: We can compare the stability of coordination complexes with same metal ion in same oxidation state…

Q: mixture of Me₂NC 1₂PPh₂ and and KSCN with K₂[Pd] gives a square planar complex A. Identify the…

A: s and p both form pie bonding with complex and pie bonding capacity of sulphur is greater…

Q: The reaction of [Co(NH3)4CI2] with H20 is 103 times faster than the reaction of (Co(NH3)sCI]°. By…

A: Id is dissociative mechanism while Ia is associative mechanism. The reaction involving complex…

Q: b. HO tBuOOH TI[OCH(CH3)2]4 (+) - DET

A: Given data: Here (+)-DET is used, so epoxidation will happen in the Re face. is the oxidising agent…

Q: (a) Put in order of increasing rate of substitution by NH3 in the following complexes (a)…

A:

Q: Q 4. Which of these complexes conduct more electricity K3[CuCls]or [Co(NH3),Cl3] Explain?.

A:

Q: (a) Give the formal oxidation number and the d-electron count of the transition element and the…

A: In metal complexes, the central transition metal is often surrounded by ligands, which are neutral…

Q: Using the data below, which of the following complexes undergoes the slowest ligand dissociation…

A: Tertiary phosphine ligands: The tertiary phosphine ligands with varying sizes can affect the…

Q: Write the name for Cr(CO)5. Group of answer choices pentacarbonlychromium (V) pentacarbonlychromium…

A: Coordination complexes are named as: Ligands are listed in alphabetical order by name. Next comes…

Q: 26. Which one of the following complexes exhibits optical isomerism? (a) cis-[PtCl2(NH3)2] (b)…

A: Optical isomers are stereoisomers that are related via non-superimposable mirror images of each…

Q: [RhCl3]       RhCl3 & [RhHCl3(PMe3)2]¯       [RhHCl3(PMe3)2]¯       [RhHCl3]3¯

A: We have to find which complex(es) is NOT stable

Q: [ Select ] unpaired d electrons present in the [Rh(NH3)4CI2]* There are a complex, which is a low…

A: We have to 1st [Select] options include: 0,1,2,3 or 4 2nd [Select] options include: unaffected by,…

Q: Some reactions in organometallic chemistry involve the insertion of small molecules into…

A: In the given complex, Tc (Technitium) has a coordination number of 5 and is coordinated to four…

Q: The_isomer of [Fe(NH3)3CI3] has C2y symmetry. mer fac

A: Welcome to bartleby!

Q: The following electron transfer reaction occurs by an inner sphere mechanism. [Fe(OH₂)6]²+ +…

A: i) It contains a bridging ligand.Br is the bridging ligand in given reaction. ii) Electron transfer…

Q: Give the systematic name of this coordination compound. Omit -N or -κN type designations.…

A: Answer: Given compound is a coordination compound and we have to write down its name according to…

Q: Which option indicates, in order, whether the following compounds obey the effective atomic number…

A: EAN for K2[HgI4] is determined as shown below. Therefore, K2[HgI4] obeys the effective atomic number…

Q: 9.a) Reduction of [Co(NH;)«J** by [Cr(H2O)«J²* is very much slow that the reduction with [V(NH3)]**…

A: a).  The reduction of [Co(NH3)6]3+ by [Cr(H2O)6]2+ is much slower than the reduction with[V(NH3)6]2+…

Q: b) A student finds two bottles of colourless liquid containing the same molecule (shown below), but…

A: Concepts of chirality.

Q: Draw all isomers of each species. Cleary indicate chiral enantiomers. Name the isomers using the…

A: Guideline message: As per the guidelines, in case of a multipart question, first three subparts need…

Q: How many unpaired electrons are in [ Fe { C triple bond CSi(CH3)3}64-]  please explain completely

A: Unpaired electrons is zero. (0)

Q: Determine how many T-donor ligands and potential n-bonds of the molecule above?

A: The π donor ligands are those which can donate electrons to σσ* and ππ* molecular orbitals. Oxides,…

Q: please draw d - d splitting of [Co[H2O]6]2+ and [CoC14] 2-

A: Given  cobalt complexes [Co(H2O)6]2+ and [Co(Cl)4]2- Draw the d-d splitting of complex.

Q: 12. How can cis-[Pt(NH3)2B12] be prepared? Use the trans-directing series shown below co, CN', C2H4…

A: Option A) is the best choice

Q: Which of the following complexes may undergo b-H elimination O Al [(CH,Si(CH3)al2 (Et) O…

A:

Q: A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction:…

A: Monodentate ligands bind to other molecule through only one donor atom and bidentate ligands bind to…

Q: 4) Rank the following sigma complexes in order of increasing stability. NO₂ A + H H3CO. Br B H -Br H…

A: Answer of this question :-  Sigma complex :- Sigma complex refers to an arenium ion. The suffix…

Q: Which of the comple: - (a) [Cr(edta)];, - (b) [Ru(en),]²+;

A: The substance which possesses symmetric elements are called as achiral molecules. The substance…

Q: What is the reducible representation for C4v of [MNI(CO5)]?

A: Establish a coordinate system for the molecule, incorporating x, y, and z axes aligned through the…

Q: Give the starting material and mechanism arrows needed to produce the given product by coordination.…

A: organic reaction mechanism.

Q: what is the LFSE for [Fe(CN)6]4-? splitting parameter is  32800cm-1 pairing energy is 17600 cm-1

A:

Q: 1. Arrange the following in order of increasing molar absorptivity &, and explain your ordering. a.…

A: Metal complexes are produced by the combination of the ligands with the unshared electron pairs. The…

Q: A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction:…

A: Dissociation reaction occurs as Dissociation of ligand followed by association of ligand . Thus rate…

Q: Which of the following will exhibit cis-trans isomerism? Fe°: [Ar]4s²3d6 Cdº: [Kr]5s²4d10 Ptº:…

A: A multiple choice question based on coordination complex, which is to be accomplished.

Q: o Identify A, B, C & D; [Co(NH;);(NO2)]* + [Co(CN);}* В Hydrolisation Isomerization D

A:

Q: As ethylenediamine is added to a solution of (Compound 1) [Ni(H20)¿J²*, the water molecules are…

A: A question based on coordination complexes that is to be accomplished.

Q: 3. Which complex shows lower C-O stretching frequency, [Ni(acac)2(H2O2 or [Ni(acac)2]? Explain.

A:

Q: (b) Х + NH; —Y

A: Trans Effect is defined as the tendency of a particular group to direct the incoming group to occupy…

Q: Based on the 18-electron rule, determine the expected charge on the following: a.…

A: Given some coordination complexes, determine the charge on each complex.

Q: Draw structure of following 1. (+)-[Co(en)3] (+)-tartrate chloride pentahydrate 2..  (-)-[Co(en)3]…

A: We have to draw the structures of the given compounds:

Q: )[Ma(cO),]

A: In coordination compound,  CO bond length depends on metal atom.

Q: in the mechanism of ligand exchange in the following reaction, [Co(NH3)6]2+ + co the common…

A: The correct option is:

Q: 15. Identify which of the complexes below can exist as enantiomers. For each, draw the enantiomer…

A: Enantiomers are a pair molecules who are mirror image to each other, but non superimposible.If a…

Q: Draw the structure of the following compounds and indicate the formal oxidation state and the number…

A: Note: Since you have posted a question with multiple sub-parts, we will provide the solution only to…

Q: draw the resonace structure of [ch3(och3)2]+

A: Given is, draw resonance structure of [ CH3C(OCH3)2]+

Q: answer both will upvote

A: Answer : We will determine the stability of compound with the help of EAN rule.  EAN rule states…

Coordination Chemistry

It is a part of chemistry, in which the study of compounds that have central atoms surrounded by molecules or ions, known as ligand, is known as coordination chemistry.