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A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4- and why? C. How does the chelate effect affects the rate of a reaction?

A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4- and why? C. How does the chelate effect affects the rate of a reaction?

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4- and why? C. How does the chelate effect affects the rate of a reaction? D. An the electron transfer mediated through a bridging ligand. Marcus Theory was developed as to provide evidence for mechanisms in electron transfer reactions. The Frank- Condon principle is used to explain the mechanism of (inner, outer) sphere mechanism involves (inner, outer) sphere an (inner, outer) sphere reaction.
Transcribed Image Text:A. Put the following complexes in decreasing order of reactions rates under a dissociation reaction: [CuCl6]-5, [VCI6]-3 and [CoCl6]4. Justify. B. Which complexes is more labile, [Mn(H2O)6]2+ or [Mn(NC)6]4- and why? C. How does the chelate effect affects the rate of a reaction? D. An the electron transfer mediated through a bridging ligand. Marcus Theory was developed as to provide evidence for mechanisms in electron transfer reactions. The Frank- Condon principle is used to explain the mechanism of (inner, outer) sphere mechanism involves (inner, outer) sphere an (inner, outer) sphere reaction.
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