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5. Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). H H₂N НО. OH OH OH NH₂

5. Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). H H₂N НО. OH OH OH NH₂

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Ligand Denticity Analysis** **Question 5:** Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). **Ligand Structures:** 1. **Structure 1:** - This structure features two NH₂ groups at either end of the ligand, connected by a chain containing an NH group. - Since there are three potential donor atoms (two NH₂ and one NH), this ligand is capable of binding to a metal at multiple sites, making it tridentate. 2. **Structure 2:** - This structure appears to contain several carboxyl (COOH) and amide (NH) groups. - The presence of multiple potential binding sites (notably, the oxygen atoms from carboxyl groups and possibly nitrogen atoms from amide groups) suggests that this ligand can bind to a metal ion at multiple points. Given the number of carboxyl and amide groups, this is likely a hexadentate ligand, with six potential sites for coordination. **Summary:** - The first ligand (two NH₂ groups and one NH group) is tridentate. - The second ligand (multiple COOH and NH groups) is hexadentate.
Transcribed Image Text:**Ligand Denticity Analysis** **Question 5:** Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). **Ligand Structures:** 1. **Structure 1:** - This structure features two NH₂ groups at either end of the ligand, connected by a chain containing an NH group. - Since there are three potential donor atoms (two NH₂ and one NH), this ligand is capable of binding to a metal at multiple sites, making it tridentate. 2. **Structure 2:** - This structure appears to contain several carboxyl (COOH) and amide (NH) groups. - The presence of multiple potential binding sites (notably, the oxygen atoms from carboxyl groups and possibly nitrogen atoms from amide groups) suggests that this ligand can bind to a metal ion at multiple points. Given the number of carboxyl and amide groups, this is likely a hexadentate ligand, with six potential sites for coordination. **Summary:** - The first ligand (two NH₂ groups and one NH group) is tridentate. - The second ligand (multiple COOH and NH groups) is hexadentate.
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