5. Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). H H₂N НО. OH OH OH NH₂

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
Question
**Ligand Denticity Analysis**

**Question 5:** Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.).

**Ligand Structures:**

1. **Structure 1:**
   - This structure features two NH₂ groups at either end of the ligand, connected by a chain containing an NH group. 
   - Since there are three potential donor atoms (two NH₂ and one NH), this ligand is capable of binding to a metal at multiple sites, making it tridentate.

2. **Structure 2:**
   - This structure appears to contain several carboxyl (COOH) and amide (NH) groups.
   - The presence of multiple potential binding sites (notably, the oxygen atoms from carboxyl groups and possibly nitrogen atoms from amide groups) suggests that this ligand can bind to a metal ion at multiple points. Given the number of carboxyl and amide groups, this is likely a hexadentate ligand, with six potential sites for coordination. 

**Summary:**
- The first ligand (two NH₂ groups and one NH group) is tridentate.
- The second ligand (multiple COOH and NH groups) is hexadentate.
Transcribed Image Text:**Ligand Denticity Analysis** **Question 5:** Determine the denticity of each ligand (i.e., is it monodentate, bidentate, etc.). **Ligand Structures:** 1. **Structure 1:** - This structure features two NH₂ groups at either end of the ligand, connected by a chain containing an NH group. - Since there are three potential donor atoms (two NH₂ and one NH), this ligand is capable of binding to a metal at multiple sites, making it tridentate. 2. **Structure 2:** - This structure appears to contain several carboxyl (COOH) and amide (NH) groups. - The presence of multiple potential binding sites (notably, the oxygen atoms from carboxyl groups and possibly nitrogen atoms from amide groups) suggests that this ligand can bind to a metal ion at multiple points. Given the number of carboxyl and amide groups, this is likely a hexadentate ligand, with six potential sites for coordination. **Summary:** - The first ligand (two NH₂ groups and one NH group) is tridentate. - The second ligand (multiple COOH and NH groups) is hexadentate.
Expert Solution
trending now

Trending now

This is a popular solution!

steps

Step by step

Solved in 3 steps with 3 images

Blurred answer
Knowledge Booster
Coordination Complexes
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Similar questions
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY