A low-intensity peak at m/Z = 31 can be seen in the mass spectrum of methyl acetate in Figure 3. Propose a fragment that could originate from methyl acetate and be responsible for this peak.
A low-intensity peak at m/Z = 31 can be seen in the mass spectrum of methyl acetate in Figure 3. Propose a fragment that could originate from methyl acetate and be responsible for this peak.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:100
80
H3C
60
40
CH3
H3C
20
H3C
0.0
0.0
15
30
45
60
75
90
m/z
Figure 3. Positive ion mass spectrum of methyl acetate. Note that the peak with the greatest
relative intensity is not that of the parent ion fragment.
Note in Figure 3. that the peaks corresponding to m/Z= 29 and 42 correspond to fragments which
resulted from more than a single bond-breaking event.
Rel. Intensity
0=U

Transcribed Image Text:A low-intensity peak at m/Z = 31 can be seen in the mass spectrum of methyl acetate in
Figure 3. Propose a fragment that could originate from methyl acetate and be responsible
for this peak.
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