(a) Interpret the variation, including the overall trend across the 3d series, of the following values of hydration enthalpies (in kJ mol'). [Ca(H2O)«]**: -2468; [Ti(H2O)kJ²*: -2700; [V(H2O)cJ²*: -2814; [Mn(H2O)«]²*: -2743; [Fe(H2O)«]*: -2843; [Co(H20)6J**: -2904; [Ni(H2O)cJ*: -2986. (b) By making use of LFSE (Ligand field stabilization energy) in tetrahedral and octahedral geometries, predict whether hausmannite mineral (Mn3O4) has a normal spinel or inverse spinel structure. Describe the structure of the mineral in detail.
(a) Interpret the variation, including the overall trend across the 3d series, of the following values of hydration enthalpies (in kJ mol'). [Ca(H2O)«]**: -2468; [Ti(H2O)kJ²*: -2700; [V(H2O)cJ²*: -2814; [Mn(H2O)«]²*: -2743; [Fe(H2O)«]*: -2843; [Co(H20)6J**: -2904; [Ni(H2O)cJ*: -2986. (b) By making use of LFSE (Ligand field stabilization energy) in tetrahedral and octahedral geometries, predict whether hausmannite mineral (Mn3O4) has a normal spinel or inverse spinel structure. Describe the structure of the mineral in detail.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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![(a) Interpret the variation, including the overall trend across the 3d series, of the following
values of hydration enthalpies (in kJ mol·'). [Ca(H2O)«]²*: -2468; [Ti(H2O)«J*: -2700;
[V(H2O)«]**: -2814; [Mn(H2O)6]**: -2743; [Fe(H2O)«]²+: -2843; [Co(H20)6]**: -2904;
[Ni(H2O)c]*: -2986.
(b) By making use of LFSE (Ligand field stabilization energy) in tetrahedral and octahedral
geometries, predict whether hausmannite mineral (Mn3O4) has a normal spinel or inverse
spinel structure. Describe the structure of the mineral in detail.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F9b9a147a-5866-406f-8e5c-c35be48ea749%2Fd4bd572d-4fcf-4b8e-b7bd-bf59e46e8f15%2F5l0inf_processed.png&w=3840&q=75)
Transcribed Image Text:(a) Interpret the variation, including the overall trend across the 3d series, of the following
values of hydration enthalpies (in kJ mol·'). [Ca(H2O)«]²*: -2468; [Ti(H2O)«J*: -2700;
[V(H2O)«]**: -2814; [Mn(H2O)6]**: -2743; [Fe(H2O)«]²+: -2843; [Co(H20)6]**: -2904;
[Ni(H2O)c]*: -2986.
(b) By making use of LFSE (Ligand field stabilization energy) in tetrahedral and octahedral
geometries, predict whether hausmannite mineral (Mn3O4) has a normal spinel or inverse
spinel structure. Describe the structure of the mineral in detail.
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