A feed mixture containing 50 wt% n-heptane and 50 wt% methyl cyclohexane (MCH) is to be separated by liquid-liquid extraction into one product containing 92.5 wt% methylcyclohexane and another containing 7.5 wt% methylcyclo- hexane. Aniline will be used as the solvent. (a) What is the minimum number of theoretical stages necessary to effect this separation? (b) What is the minimum extract reflux ratio? (c) If the reflux ratio is 7.0, how many theoretical contacts will be required? Liquid-liquid equilibrium data for the system n-heptane-methy! cyclohexane-aniline at 25°C and at 1 atm (101 kPa) Hydrocarbon Layer Solvent Layer Weight percent MCH, solvent- free basis Pounds aniline/ pound solvent- free mixture Weight percent MCH, solvent- free basis Pounds aniline/ pound solvent- free mixture

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A feed mixture containing 50 wt% n-heptane and 50 wt% methyl cyclohexane
(MCH) is to be separated by liquid-liquid extraction into one product containing
92.5 wt% methylcyclohexane and another containing 7.5 wt% methylcyclo-
hexane. Aniline will be used as the solvent.
(a) What is the minimum number of theoretical stages necessary to effect this
separation?
(b) What is the minimum extract reflux ratio?
(c) If the reflux ratio is 7.0, how many theoretical contacts will be required?
Liquid-liquid equilibrium data for the system n-heptane-methyl
cyclohexane-aniline at 25°C and at 1 atm (101 kPa)
Hydrocarbon Layer
Solvent Layer
Weight percent
MCH, solvent-
free basis
Pounds aniline/
pound solvent-
free mixture
Pounds aniline/
Weight percent
MCH, solvent-
free basis
pound solvent-
free mixture
0.0
0.0799
0.0
9.9
20.2
23.9
0.0836
0.087
0.0894
15.12
13.72
11.5
11.8
33.8
37.0
50.6
60.0
11.34
36.9
0.094
9.98
9.0
8.09
44.5
0.0952
0.0989
0.1062
50.5
67.3
66.0
76.7
84.3
88.8
6.83
74.6
79.7
82.1
93.9
100.0
0.1111
6.45
0.1135
0.116
0.1272
0.135
6.0
90.4
5.9
96.2
100.0
5.17
4.92
Transcribed Image Text:A feed mixture containing 50 wt% n-heptane and 50 wt% methyl cyclohexane (MCH) is to be separated by liquid-liquid extraction into one product containing 92.5 wt% methylcyclohexane and another containing 7.5 wt% methylcyclo- hexane. Aniline will be used as the solvent. (a) What is the minimum number of theoretical stages necessary to effect this separation? (b) What is the minimum extract reflux ratio? (c) If the reflux ratio is 7.0, how many theoretical contacts will be required? Liquid-liquid equilibrium data for the system n-heptane-methyl cyclohexane-aniline at 25°C and at 1 atm (101 kPa) Hydrocarbon Layer Solvent Layer Weight percent MCH, solvent- free basis Pounds aniline/ pound solvent- free mixture Pounds aniline/ Weight percent MCH, solvent- free basis pound solvent- free mixture 0.0 0.0799 0.0 9.9 20.2 23.9 0.0836 0.087 0.0894 15.12 13.72 11.5 11.8 33.8 37.0 50.6 60.0 11.34 36.9 0.094 9.98 9.0 8.09 44.5 0.0952 0.0989 0.1062 50.5 67.3 66.0 76.7 84.3 88.8 6.83 74.6 79.7 82.1 93.9 100.0 0.1111 6.45 0.1135 0.116 0.1272 0.135 6.0 90.4 5.9 96.2 100.0 5.17 4.92
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