(a) Explain the following observations: (1) (ii) (iii) For a given metal ion, the thermodynamic stability of polydentate ligand is greater than that of a complex containing a corresponding number of comparable monodentate ligands. The K, value for [Cu(NH3)4] and [Cu(en)₂]²* is 1.1 x 10¹3 and 1.0 x 1020, respectively. The compound Pt(CO), is known but cluster (CO)3Pt(μ-Cl)₂Pt(CO) has never been prepared.
(a) Explain the following observations: (1) (ii) (iii) For a given metal ion, the thermodynamic stability of polydentate ligand is greater than that of a complex containing a corresponding number of comparable monodentate ligands. The K, value for [Cu(NH3)4] and [Cu(en)₂]²* is 1.1 x 10¹3 and 1.0 x 1020, respectively. The compound Pt(CO), is known but cluster (CO)3Pt(μ-Cl)₂Pt(CO) has never been prepared.
Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter20: Chemistry Of Selected Transition Elements And Coordination Compounds
Section: Chapter Questions
Problem 11QRT
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