a) Consider the following reaction: [M(H₂O)]³+ + 2 en → [M(en):]++ 6H₂O (M-a metal ion; en = 1,2-diaminoethane) For this reaction: AHⓇ-56.5 kJ mol¹; AS-0.014 kJ mol-¹K¹. Calculate the AG" for this reaction at 298 K. b) Would you predict the AG" for the formation for [M(en):) to be higher or lower than the AGº for the formation of [M(NH3)4]? Explain your answer. c) For the ligand substitution reaction of [M(OH₂)] (where M-a metal ion) with a halide, X, Kn = 36.0, Kn=4.0, Ko=1.0 and Ka-2.5. What can be inferred by the fact that Ku is greater than Kn?

a) Consider the following reaction: [M(H₂O)]³+ + 2 en → [M(en):]++ 6H₂O (M-a metal ion; en = 1,2-diaminoethane) For this reaction: AHⓇ-56.5 kJ mol¹; AS-0.014 kJ mol-¹K¹. Calculate the AG" for this reaction at 298 K. b) Would you predict the AG" for the formation for [M(en):) to be higher or lower than the AGº for the formation of [M(NH3)4]? Explain your answer. c) For the ligand substitution reaction of [M(OH₂)] (where M-a metal ion) with a halide, X, Kn = 36.0, Kn=4.0, Ko=1.0 and Ka-2.5. What can be inferred by the fact that Ku is greater than Kn?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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