2. Consider the following reaction: 4 HCN(/) + 5 O2(g) → 2 H₂O(g) + 4 CO₂(g) + 2 N2(g) (a) Using the following data, calculate AG," for this reaction at 25 °C. Compound AG (kJ/mol) AH (kJ/mol) Sm (J/mol-K) HCN(/) +124.7 +108.87 112.84 O2(g) 205.138 N2(g) 191.61 H₂O(/) -237.13 -285.83 69.91 H2O(g) -228.57 -241.82 188.83 CO2(g) -394.39 -393.51 213.74 (b) At this temperature, in which direction is this reaction spontaneous? How do you know? (c) At what temperature, in °C, does this reaction become spontaneous in the opposite direction? (d) If the standard chemical potential at SATP of H2O(g) is -16.5 kJ mol¹, what is the chemical potential of H2O(g) at 75. kPa, in kJ/mol? What does this tell you about the potential of H2O to participate in chemical activity as the pressure is changing?
2. Consider the following reaction: 4 HCN(/) + 5 O2(g) → 2 H₂O(g) + 4 CO₂(g) + 2 N2(g) (a) Using the following data, calculate AG," for this reaction at 25 °C. Compound AG (kJ/mol) AH (kJ/mol) Sm (J/mol-K) HCN(/) +124.7 +108.87 112.84 O2(g) 205.138 N2(g) 191.61 H₂O(/) -237.13 -285.83 69.91 H2O(g) -228.57 -241.82 188.83 CO2(g) -394.39 -393.51 213.74 (b) At this temperature, in which direction is this reaction spontaneous? How do you know? (c) At what temperature, in °C, does this reaction become spontaneous in the opposite direction? (d) If the standard chemical potential at SATP of H2O(g) is -16.5 kJ mol¹, what is the chemical potential of H2O(g) at 75. kPa, in kJ/mol? What does this tell you about the potential of H2O to participate in chemical activity as the pressure is changing?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2. Consider the following reaction: 4 HCN(/) + 5 O2(g) → 2 H₂O(g) + 4 CO₂(g) + 2 N2(g)
(a) Using the following data, calculate AG," for this reaction at 25 °C.
Compound AG (kJ/mol) AH (kJ/mol) Sm (J/mol-K)
HCN(/)
+124.7
+108.87
112.84
O2(g)
205.138
N2(g)
191.61
H₂O(/)
-237.13
-285.83
69.91
H2O(g)
-228.57
-241.82
188.83
CO2(g)
-394.39
-393.51
213.74
(b) At this temperature, in which direction is this reaction spontaneous? How do you know?
(c) At what temperature, in °C, does this reaction become spontaneous in the opposite
direction?
(d) If the standard chemical potential at SATP of H2O(g) is -16.5 kJ mol¹, what is the
chemical potential of H2O(g) at 75. kPa, in kJ/mol? What does this tell you about the
potential of H2O to participate in chemical activity as the pressure is changing?
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