A chemical engineer is studying the following reaction: HCH,CO,(aq)+CH,NH,(aq) → CH3CO,(aq)+CH3NH;(aq) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound concentration expected change in concentration vessel HCH,CO, 0.94 M t increase OI decrease (no change) CH,NH, 1.01 M t increase OI decrease O (no change) A CH,CO, 0.56 M O t increase OI decrease O (no change) CH,NH, 0.22 M O t increase OI decrease (no change) HCH,CO, 1.05 M t increase I decrease O (no change) CH;NH, 1.12 M O t increase OI decrease O (no change) CH,Co, O t increase 0.45 M I decrease (no change) CH.NH 0.11 M t increase OI decrease O (no change)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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reaction
compound
concentration
expected change in concentration
vessel
HCH,CO,
0.94 M
f increase
I decrease
(no change)
CH,NH,
1.01 M
f increase
I decrease
(no change)
A
0.56 M
CH,CO,
f increase
I decrease
(no change)
+
CH;NH,
0.22 M
f increase
I decrease
(no change)
HCH,CO,
1.05 M
f increase
I decrease
(no change)
CH,NH,
1.12 M
↑ increase
I decrease
(no change)
CH,CO,
0.45 M
f increase
decrease
(no change)
+
CH,NH,
0.11 M
↑ increase
O I decrease
O (no change)
HCH,CO,
0.25 M
f increase
I decrease
(no change)
CH,NH,
0.32 M
f increase
I decrease
(no change)
C
CH,CO,
1.25 M
↑ increase
I decrease
(no change)
CH,NH,
0.91 M
↑ increase
O I decrease
(no change)
Transcribed Image Text:reaction compound concentration expected change in concentration vessel HCH,CO, 0.94 M f increase I decrease (no change) CH,NH, 1.01 M f increase I decrease (no change) A 0.56 M CH,CO, f increase I decrease (no change) + CH;NH, 0.22 M f increase I decrease (no change) HCH,CO, 1.05 M f increase I decrease (no change) CH,NH, 1.12 M ↑ increase I decrease (no change) CH,CO, 0.45 M f increase decrease (no change) + CH,NH, 0.11 M ↑ increase O I decrease O (no change) HCH,CO, 0.25 M f increase I decrease (no change) CH,NH, 0.32 M f increase I decrease (no change) C CH,CO, 1.25 M ↑ increase I decrease (no change) CH,NH, 0.91 M ↑ increase O I decrease (no change)
A chemical engineer is studying the following reaction:
+
HCH;CO2(aq)+CH,NH,(aq) → CH;CO,(aq)+CH;NH,(aq)
At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93.
The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the
mixture inside each vessel from time to time. His first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time he measures the compositions.
reaction
compound
concentration
expected change in concentration
vessel
HCH,CO,
0.94 M
f increase
I decrease
(no change)
CH,NH,
1.01 M
f increase
I decrease
(no change)
A
CH,CO,
0.56 M
f increase
I decrease
(no change)
CH,NH,
0.22 M
f increase
OI decrease
O (no change)
HCH,CO,
1.05 M
f increase
I decrease
(no change)
CH,NH,
1.12 M
f increase
I decrease
(no change)
В
CH,CO,
0.45 M
f increase
I decrease
(no change)
CH,NH,
0.11 M
f increase
I decrease
(no change)
Transcribed Image Text:A chemical engineer is studying the following reaction: + HCH;CO2(aq)+CH,NH,(aq) → CH;CO,(aq)+CH;NH,(aq) At the temperature the engineer picks, the equilibrium constant K, for this reaction is 0.93. The engineer charges ("fills") four reaction vessels with acetic acid and methylamine, and lets the reaction begin. He then measures the composition of the mixture inside each vessel from time to time. His first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time he measures the compositions. reaction compound concentration expected change in concentration vessel HCH,CO, 0.94 M f increase I decrease (no change) CH,NH, 1.01 M f increase I decrease (no change) A CH,CO, 0.56 M f increase I decrease (no change) CH,NH, 0.22 M f increase OI decrease O (no change) HCH,CO, 1.05 M f increase I decrease (no change) CH,NH, 1.12 M f increase I decrease (no change) В CH,CO, 0.45 M f increase I decrease (no change) CH,NH, 0.11 M f increase I decrease (no change)
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