A chemical engineer is studying the following reaction: H₂(g) + Cl₂(g) → 2 HCl(g) At the temperature the engineer picks, the equilibrium constant. K for this reaction is 0.67. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. She then measures the composition of the mixtur inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B С compound CL HC1 C1₂ HC1 C1₂ HCI pressure 2.46 am 4.94 atm 1.73 atm 1.68 atm 4.16 atm 3.31 atm 2.07 atm 4.55 atm 2.52 atm expected change in pressure O ↓ decrease O↓ decrease O ↓ decrease O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase ↓ decrease O↓ decrease decrease ↓ decrease decrease decrease O (no change) O (no change) O (no change) (no change) O (no change) (no change) (no change) (no change) O (no change)

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Chapter12: Chemical Equilibrium
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Problem 12.41PAE: Because calcium carbonate is a sink for CO32- in a lake, the student in Exercise 12.39 decides to go...
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A chemical engineer is studying the following reaction:
H₂(g) + Cl₂(g) → 2 HCl(g)
At the temperature the engineer picks, the equilibrium constant. K for this reaction is 0.67.
The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. She then measures the composition of the mixture
inside each vessel from time to time. Her first set of measurements are shown in the table below.
Predict the changes in the compositions the engineer should expect next time she measures the compositions.
reaction
vessel
A
B
C
compound
CL
HC1
C1₂
HC1
P
C1₂
HC1
pressure
2.46 am
4.94 atm
1.73 atm
1.68 atm
4.16 atm
3.31 atm
2.07 atm
4.55 atm
2.52 atm
expected change in pressure
O ↓ decrease
O↓ decrease
O ↓ decrease
O ↑ increase
O ↑ increase
O ↑ increase
O ↑ increase
O ↑ increase
O ↑ increase
O ↑ increase
O ↑ increase
O ↑ increase
↓ decrease
O↓ decrease
decrease
↓ decrease
↓ decrease
O ↓ decrease
O (no change)
O (no change)
O (no change)
(no change)
O (no change)
(no change)
(no change)
(no change)
O (no change)
Transcribed Image Text:A chemical engineer is studying the following reaction: H₂(g) + Cl₂(g) → 2 HCl(g) At the temperature the engineer picks, the equilibrium constant. K for this reaction is 0.67. The engineer charges ("fills") three reaction vessels with hydrogen and chlorine, and lets the reaction begin. She then measures the composition of the mixture inside each vessel from time to time. Her first set of measurements are shown in the table below. Predict the changes in the compositions the engineer should expect next time she measures the compositions. reaction vessel A B C compound CL HC1 C1₂ HC1 P C1₂ HC1 pressure 2.46 am 4.94 atm 1.73 atm 1.68 atm 4.16 atm 3.31 atm 2.07 atm 4.55 atm 2.52 atm expected change in pressure O ↓ decrease O↓ decrease O ↓ decrease O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase O ↑ increase ↓ decrease O↓ decrease decrease ↓ decrease ↓ decrease O ↓ decrease O (no change) O (no change) O (no change) (no change) O (no change) (no change) (no change) (no change) O (no change)
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