(a) Calculate the mole fraction composition of the initial terpolymer which would be formed from the radical polymerization of a feed containing 0.414 mole fraction methacrylonitrile (M1), 0.424 mole fraction styrene (M2), and 0.162 mole fraction a-methyl styrene (M3). (b) What fraction of styrene sequences in this copolymer contain 2 or more styrene units ? Data M/M2 : r1 = 0.44, r2 = 0.37; M1/M3: r1 = 0.38, r2 = 0.53; M2/M3: 1 = 1.124, r2 = 0.627.] [Ans. (a) Fi = 0.443, F2 = 0.403, F3 = 0.154; (b) 0.23] %3D %3D %3D

Introduction to Chemical Engineering Thermodynamics
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Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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7.14 (a) Calculate the mole fraction composition of the initial terpolymer which would
be formed from the radical polymerization of a feed containing 0.414 mole fraction
methacrylonitrile (M1), 0.424 mole fraction styrene (M2), and 0.162 mole fraction
a-methyl styrene (M3). (b) What fraction of styrene sequences in this copolymer
contain 2 or more styrene units ? [Data M/M2: rị
r = 0.38, r2 = 0.53; M2/M3: 11
[Ans. (a) Fi
0.44, r2 =
0.37; M/M3:
%3D
1.124, r2 0.627.]
0.443, F2 0.403, F3 0.154; (b) 0.23]
%3D
%3D
%3D
%3D
%3D
Transcribed Image Text:7.14 (a) Calculate the mole fraction composition of the initial terpolymer which would be formed from the radical polymerization of a feed containing 0.414 mole fraction methacrylonitrile (M1), 0.424 mole fraction styrene (M2), and 0.162 mole fraction a-methyl styrene (M3). (b) What fraction of styrene sequences in this copolymer contain 2 or more styrene units ? [Data M/M2: rị r = 0.38, r2 = 0.53; M2/M3: 11 [Ans. (a) Fi 0.44, r2 = 0.37; M/M3: %3D 1.124, r2 0.627.] 0.443, F2 0.403, F3 0.154; (b) 0.23] %3D %3D %3D %3D %3D
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