A + B → C [A](M)[B](M)Initial Rate (M/h) 0.200 0.221 122 0.893 0.221 230 0.200 0.409 858 Find the order with respect to A. Round to the nearest whole number.
A + B → C [A](M)[B](M)Initial Rate (M/h) 0.200 0.221 122 0.893 0.221 230 0.200 0.409 858 Find the order with respect to A. Round to the nearest whole number.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Reaction Rate Analysis
**Reaction: A + B → C**
Below is the data table summarizing the concentrations of reactants A and B, and the initial rate of product formation, C. The rate of C formed is given in Molarity per hour (M/h).
| [A] (M) | [B] (M) | Initial Rate (M/h) |
|---------|---------|--------------------|
| 0.200 | 0.221 | 122 |
| 0.893 | 0.221 | 230 |
| 0.200 | 0.409 | 858 |
**Objective:**
Determine the order of reaction with respect to reactant A. Round to the nearest whole number.
**Analysis:**
To determine the order of the reaction with respect to A, you should:
1. Compare the change in the initial rate when the concentration of A is altered, keeping concentration of B constant.
2. Utilize the rate law expression \( \text{Rate} = k [A]^m [B]^n \), where:
- \( k \) is the rate constant
- \( m \) and \( n \) are the orders of the reaction with respect to A and B, respectively
**Steps:**
1. From the table, identify experiments where the concentration of B is constant and only the concentration of A changes.
2. Calculate the ratio of rates and the ratio of the concentrations of A for these experiments and determine the reaction order.
For example, between the first and second experiments:
\[ \frac{230}{122} \approx 1.89 \]
\[ \frac{0.893}{0.200} \approx 4.465 \]
Using the rate law expression:
\[ \left( \frac{0.893}{0.200} \right)^m = \frac{230}{122} \]
\[ (4.465)^m \approx 1.89 \]
\[ m \approx \log_{4.465}(1.89) \]
\[ m \approx 0.5 \]
Round 0.5 to the nearest whole number to get the order of the reaction with respect to A.
**Conclusion:**
The order of the reaction with respect to A is approximately 0 (rounded to the nearest whole number).
Please note this is an approximation and for precise calculations further](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F8c8d8a42-8de4-4466-9c46-ae253053e314%2F08ac5de5-54ee-4c17-ba22-faf47584ac81%2Fupg9f4.png&w=3840&q=75)
Transcribed Image Text:### Reaction Rate Analysis
**Reaction: A + B → C**
Below is the data table summarizing the concentrations of reactants A and B, and the initial rate of product formation, C. The rate of C formed is given in Molarity per hour (M/h).
| [A] (M) | [B] (M) | Initial Rate (M/h) |
|---------|---------|--------------------|
| 0.200 | 0.221 | 122 |
| 0.893 | 0.221 | 230 |
| 0.200 | 0.409 | 858 |
**Objective:**
Determine the order of reaction with respect to reactant A. Round to the nearest whole number.
**Analysis:**
To determine the order of the reaction with respect to A, you should:
1. Compare the change in the initial rate when the concentration of A is altered, keeping concentration of B constant.
2. Utilize the rate law expression \( \text{Rate} = k [A]^m [B]^n \), where:
- \( k \) is the rate constant
- \( m \) and \( n \) are the orders of the reaction with respect to A and B, respectively
**Steps:**
1. From the table, identify experiments where the concentration of B is constant and only the concentration of A changes.
2. Calculate the ratio of rates and the ratio of the concentrations of A for these experiments and determine the reaction order.
For example, between the first and second experiments:
\[ \frac{230}{122} \approx 1.89 \]
\[ \frac{0.893}{0.200} \approx 4.465 \]
Using the rate law expression:
\[ \left( \frac{0.893}{0.200} \right)^m = \frac{230}{122} \]
\[ (4.465)^m \approx 1.89 \]
\[ m \approx \log_{4.465}(1.89) \]
\[ m \approx 0.5 \]
Round 0.5 to the nearest whole number to get the order of the reaction with respect to A.
**Conclusion:**
The order of the reaction with respect to A is approximately 0 (rounded to the nearest whole number).
Please note this is an approximation and for precise calculations further
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