A 60(1 ) : 40(2) liquid blend of unknown compound A (1) and B (2) is in equilibrium with its vapor at 291.2 oF. At this temperature, an azeotrope is formed in which x1az = 0.294 and that the saturation pressures of the first and second component is equal to 0.742 atm and 0.312 atm respectively. If the natural logarithm of activity coefficient of a given component is equal to the product of one parameter Margules coefficient, A multiplied by the square of the other component’s liquid mole fraction; solved for the following : a. The Margules coefficient, A b. Equilibrium pressure P c. Vapor composition of component 1
A 60(1 ) : 40(2) liquid blend of unknown compound A (1) and B (2) is in equilibrium with its vapor at 291.2 oF. At this temperature, an azeotrope is formed in which x1az = 0.294 and that the saturation pressures of the first and second component is equal to 0.742 atm and 0.312 atm respectively. If the natural logarithm of activity coefficient of a given component is equal to the product of one parameter Margules coefficient, A multiplied by the square of the other component’s liquid mole fraction; solved for the following : a. The Margules coefficient, A b. Equilibrium pressure P c. Vapor composition of component 1
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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A 60(1 ) : 40(2) liquid blend of unknown compound A (1) and B (2) is in equilibrium with its vapor at 291.2 oF. At this temperature, an azeotrope is formed in which x1az = 0.294 and that the saturation pressures of the first and second component is equal to 0.742 atm and 0.312 atm respectively.
If the natural logarithm of activity coefficient of a given component is equal to the product of one parameter Margules coefficient, A multiplied by the square of the other component’s liquid mole fraction; solved for the following :
a. The Margules coefficient, A
b. Equilibrium pressure P
c. Vapor composition of component 1
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