A 100 mL solution of 0.010 M Ce+ in 1 M HC1O4 is mixed with varying amounts of 0.040 M Cu*. The potential of the resulting solution is monitored by the following voltaic cell: Pt (s) | solution mixture || Ag/AgCl Half-Reactions E° (V) Cu* (aq) + e- 2 Cu (s) Cu2" (aq) + e- 2 Cu* (aq) Cet (aq) + e- 2 Ce* (ag) 0.521 0.153 1.61 a. Select the relevant half-reaction data from above to determine if Ce* reacts with Cu*. If it does react, determine the balanced reaction. b. Calculate the expected voltaic cell potential (Ecell) when 30 mL of 0.040 M Cu* is mixed with 100 mL solution of 0.010 M Ce+ in 1 M HCIO4. c. Calculate the expected voltaic cell potential (Ecell) when 15 mL of 0.040 M Cu* is mixed with 100 mL solution of 0.010 M Ce*+ in 1 M HCIO4.

A 100 mL solution of 0.010 M Ce+ in 1 M HC1O4 is mixed with varying amounts of 0.040 M Cu. The potential of the resulting solution is monitored by the following voltaic cell: Pt (s) | solution mixture || Ag/AgCl Half-Reactions E° (V) Cu (aq) + e- 2 Cu (s) Cu2" (aq) + e- 2 Cu* (aq) Cet (aq) + e- 2 Ce* (ag) 0.521 0.153 1.61 a. Select the relevant half-reaction data from above to determine if Ce* reacts with Cu. If it does react, determine the balanced reaction. b. Calculate the expected voltaic cell potential (Ecell) when 30 mL of 0.040 M Cu is mixed with 100 mL solution of 0.010 M Ce+ in 1 M HCIO4. c. Calculate the expected voltaic cell potential (Ecell) when 15 mL of 0.040 M Cu* is mixed with 100 mL solution of 0.010 M Ce*+ in 1 M HCIO4.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Including the state of reaction (aq),(l),(g),etc Thank you