A 10.00-mL sample of blood was diluted to 100.00 mL. 10.00 mL of the resulting solution was analyzed for calcium by precipitating all of the calcium as calcium oxalate, CaC₂O4. The solid CaC₂04 was then re-dissolved in H₂SO4 and titrated with KMnO4. What is the Ca²+ ion concentration in the blood sample expressed as (milligrams Ca²+)/(mL blood) if the endpoint was reached with the addition of 1.14 mL of 0.00886 M KMnO4? 1- 5C₂042 + 2MnO4¹ + 16H¹+ → 2Mn²+ + 10CO₂ + 8H₂O

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A 10.00-mL sample of blood was diluted to 100.00 mL. 10.00 mL of the resulting solution was analyzed for calcium by
precipitating all of the calcium as calcium oxalate, CaC₂O4. The solid CaC₂O4 was then re-dissolved in H₂SO4 and
titrated with KMnO4. What is the Ca²+ ion concentration in the blood sample expressed as (milligrams Ca²+)/(mL blood)
if the endpoint was reached with the addition of 1.14 mL of 0.00886 M KMnO4?
2+
1-
5C₂04² + 2MnO4¹ + 16H¹+→2Mn²+ + 10CO₂ + 8H₂O
2
Transcribed Image Text:A 10.00-mL sample of blood was diluted to 100.00 mL. 10.00 mL of the resulting solution was analyzed for calcium by precipitating all of the calcium as calcium oxalate, CaC₂O4. The solid CaC₂O4 was then re-dissolved in H₂SO4 and titrated with KMnO4. What is the Ca²+ ion concentration in the blood sample expressed as (milligrams Ca²+)/(mL blood) if the endpoint was reached with the addition of 1.14 mL of 0.00886 M KMnO4? 2+ 1- 5C₂04² + 2MnO4¹ + 16H¹+→2Mn²+ + 10CO₂ + 8H₂O 2
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