9.11. When compound 11-A is dissolved in FS0,H at –78°C, the NMR spectrum shows that a carbocation is formed. If the solution is then allowed to warm to - 10°C, a different carbocation is formed. When the acidic solution is quenched with 15% NaOH, the first carbocation gives product 11-B, whereas the second gives 11-C. What are the likely structures of the two carbocations? CH3 Ph Ph CHPH Ph-C-C CH3 -CH3 -CH3 OH 11-A CH3 11-в СНа 11-C

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9.11. When compound 11-A is dissolved in FS0,H at –78°C, the NMR spectrum
shows that a carbocation is formed. If the solution is then allowed to warm to
- 10°C, a different carbocation is formed. When the acidic solution is quenched
with 15% NaOH, the first carbocation gives product 11-B, whereas the second
gives 11-C. What are the likely structures of the two carbocations?
CH3
Ph
Ph
CHPH
Ph-C-C
CH3
-CH3
-CH3
OH
11-A
CH3
11-в СНа
11-C
Transcribed Image Text:9.11. When compound 11-A is dissolved in FS0,H at –78°C, the NMR spectrum shows that a carbocation is formed. If the solution is then allowed to warm to - 10°C, a different carbocation is formed. When the acidic solution is quenched with 15% NaOH, the first carbocation gives product 11-B, whereas the second gives 11-C. What are the likely structures of the two carbocations? CH3 Ph Ph CHPH Ph-C-C CH3 -CH3 -CH3 OH 11-A CH3 11-в СНа 11-C
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