9.11. When compound 11-A is dissolved in FS0,H at –78°C, the NMR spectrum shows that a carbocation is formed. If the solution is then allowed to warm to - 10°C, a different carbocation is formed. When the acidic solution is quenched with 15% NaOH, the first carbocation gives product 11-B, whereas the second gives 11-C. What are the likely structures of the two carbocations? CH3 Ph Ph CHPH Ph-C-C CH3 -CH3 -CH3 OH 11-A CH3 11-в СНа 11-C
9.11. When compound 11-A is dissolved in FS0,H at –78°C, the NMR spectrum shows that a carbocation is formed. If the solution is then allowed to warm to - 10°C, a different carbocation is formed. When the acidic solution is quenched with 15% NaOH, the first carbocation gives product 11-B, whereas the second gives 11-C. What are the likely structures of the two carbocations? CH3 Ph Ph CHPH Ph-C-C CH3 -CH3 -CH3 OH 11-A CH3 11-в СНа 11-C
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question

Transcribed Image Text:9.11. When compound 11-A is dissolved in FS0,H at –78°C, the NMR spectrum
shows that a carbocation is formed. If the solution is then allowed to warm to
- 10°C, a different carbocation is formed. When the acidic solution is quenched
with 15% NaOH, the first carbocation gives product 11-B, whereas the second
gives 11-C. What are the likely structures of the two carbocations?
CH3
Ph
Ph
CHPH
Ph-C-C
CH3
-CH3
-CH3
OH
11-A
CH3
11-в СНа
11-C
Expert Solution

This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 3 steps with 2 images

Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning

Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education

Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning

Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education

Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning

Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY