9. The boss is keen to generate the methoxide catalyst on site and has identified an available 2m³ agitated reactor. This process consists of feeding 270 kg a sodium metal pellets (Mw=23) in to 1.25 m³ methanol giving a final volume of methoxide solution of 1.5m³. This is considered very dangerous, and you are keen to have not more than 90 gr of Sodium metal in the vessel at any one time. You therefore suggest a fed batch process. Literature has the following information for the metoxide formation: 1 Na + HO-Me → NaOMe +H₂ (-RNa)=0.047 [Na] 2/3 in g/L.s with [Na] the concentration of sodium metal in g/L. Assuming a constant volume that gives a conservative estimate, you predict the minimum addition time of to be: a. 1.6 hr b. 3.8 hr c. 7.4 hr V d. 18 hr e. 43 hr f. 82 hr 13

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question
9.
The boss is keen to generate the methoxide catalyst on site and has identified an available 2m³
agitated reactor. This process consists of feeding 270 kg a sodium metal pellets (Mw=23) in to
1.25 m³ methanol giving a final volume of methoxide solution of 1.5m³. This is considered very
dangerous, and you are keen to have not more than 90 gr of Sodium metal in the vessel at any one
time. You therefore suggest a fed batch process. Literature has the following information for the
metoxide formation:
1
Na + HO-Me → NaOMe +H₂
(-RNa)=0.047 [Na] 2/3 in g/L.s
with [Na] the concentration of sodium metal in g/L. Assuming a constant volume that gives
a conservative estimate, you predict the minimum addition time of to be:
a. 1.6 hr
b. 3.8 hr
c.
7.4 hr
V
d. 18 hr
e. 43 hr
f. 82 hr
13
Transcribed Image Text:9. The boss is keen to generate the methoxide catalyst on site and has identified an available 2m³ agitated reactor. This process consists of feeding 270 kg a sodium metal pellets (Mw=23) in to 1.25 m³ methanol giving a final volume of methoxide solution of 1.5m³. This is considered very dangerous, and you are keen to have not more than 90 gr of Sodium metal in the vessel at any one time. You therefore suggest a fed batch process. Literature has the following information for the metoxide formation: 1 Na + HO-Me → NaOMe +H₂ (-RNa)=0.047 [Na] 2/3 in g/L.s with [Na] the concentration of sodium metal in g/L. Assuming a constant volume that gives a conservative estimate, you predict the minimum addition time of to be: a. 1.6 hr b. 3.8 hr c. 7.4 hr V d. 18 hr e. 43 hr f. 82 hr 13
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