Homework Help is Here – Start Your Trial Now!
Engineering
Chemical Engineering
14) The gas-phase catalytic reaction A + B + C is believed to have the following rate law. -r= k (KB PAPB - KCPC) Ks 1+ KBPB+ KCPC Propose a mechanism and rate limiting step that are consistent with the rate law above. Note: for full credit, you must prove that the mechanism and rate limiting step match the rate law. where did the negative come from? Molecular adsorption Mechanism: A*A* B+* B* Desorption this is written as an A*+B*→C+* YAD=KAM (PACK-CA*) VAD,B=KAB (PBC*- rs= Ks CA*CB* CB KB sts. adsorption

14) The gas-phase catalytic reaction A + B + C is believed to have the following rate law. -r= k (KB PAPB - KCPC) Ks 1+ KBPB+ KCPC Propose a mechanism and rate limiting step that are consistent with the rate law above. Note: for full credit, you must prove that the mechanism and rate limiting step match the rate law. where did the negative come from? Molecular adsorption Mechanism: A*A* B+* B* Desorption this is written as an A*+B*→C+* YAD=KAM (PACK-CA*) VAD,B=KAB (PBC*- rs= Ks CA*CB* CB KB sts. adsorption

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
See similar textbooks
icon
Related questions
Question
14) The gas-phase catalytic reaction A + B + C is believed to have the following rate law. -r= k (KB PAPB - KCPC) Ks 1+ KBPB+ KCPC Propose a mechanism and rate limiting step that are consistent with the rate law above. Note: for full credit, you must prove that the mechanism and rate limiting step match the rate law. where did the negative come from? Molecular adsorption Mechanism: A*A* B+* B* Desorption this is written as an A*+B*→C+* YAD=KAM (PACK-CA*) VAD,B=KAB (PBC*- rs= Ks CA*CB* CB KB sts. adsorption
Transcribed Image Text:14) The gas-phase catalytic reaction A + B + C is believed to have the following rate law. -r= k (KB PAPB - KCPC) Ks 1+ KBPB+ KCPC Propose a mechanism and rate limiting step that are consistent with the rate law above. Note: for full credit, you must prove that the mechanism and rate limiting step match the rate law. where did the negative come from? Molecular adsorption Mechanism: A*A* B+* B* Desorption this is written as an A*+B*→C+* YAD=KAM (PACK-CA*) VAD,B=KAB (PBC*- rs= Ks CA*CB* CB KB sts. adsorption
Expert Solution
steps

Step by step

Solved in 2 steps

SEE SOLUTIONCheck out a sample Q&A here
Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The
SEE MORE TEXTBOOKS