89. Consider this reaction occurring at 298 K: N2O(g) + NO2(g) 3 NO(g) a. Show that the reaction is not spontaneous under standard conditions by calculating A Grxn b. If a reaction mixture contains only N2O and NO2 at partial pressures of 1.0 atm each, the reaction will be spontane- ous until some NO forms in the mixture. What maximum partial pressure of NO builds up before the reaction ceases to be spontaneous? c. Can the reaction be made more spontaneous by an increase or decrease in temperature? If so, what temperature is required to make the reaction spontaneous under standard conditions?
89. Consider this reaction occurring at 298 K: N2O(g) + NO2(g) 3 NO(g) a. Show that the reaction is not spontaneous under standard conditions by calculating A Grxn b. If a reaction mixture contains only N2O and NO2 at partial pressures of 1.0 atm each, the reaction will be spontane- ous until some NO forms in the mixture. What maximum partial pressure of NO builds up before the reaction ceases to be spontaneous? c. Can the reaction be made more spontaneous by an increase or decrease in temperature? If so, what temperature is required to make the reaction spontaneous under standard conditions?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:89. Consider this reaction occurring at 298 K:
N2O(g) + NO2(g)
3 NO(g)
a. Show that the reaction is not spontaneous under standard
conditions by calculating A Grxn
b. If a reaction mixture contains only N2O and NO2 at partial
pressures of 1.0 atm each, the reaction will be spontane-
ous until some NO forms in the mixture. What maximum
partial pressure of NO builds up before the reaction ceases to
be spontaneous?
c. Can the reaction be made more spontaneous by an increase
or decrease in temperature? If so, what temperature is
required to make the reaction spontaneous under standard
conditions?
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