57. For each reaction, calculate AHan, AS, and AGan at 25 °C and state whether or not the reaction is spontaneous. If the reac- tion is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C? a. N,0,(g) – 2 NO:(g)
57. For each reaction, calculate AHan, AS, and AGan at 25 °C and state whether or not the reaction is spontaneous. If the reac- tion is not spontaneous, would a change in temperature make it spontaneous? If so, should the temperature be raised or lowered from 25 °C? a. N,0,(g) – 2 NO:(g)
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Problem 57: Evaluation of Reaction Spontaneity at 25°C**
For each of the following reactions, calculate the changes in enthalpy (\(\Delta H^\circ_{\text{rxn}}\)), entropy (\(\Delta S^\circ_{\text{rxn}}\)), and Gibbs free energy (\(\Delta G^\circ_{\text{rxn}}\)) at 25°C. Determine whether each reaction is spontaneous under these conditions. If a reaction is not spontaneous, assess whether a change in temperature could make it spontaneous. Indicate if the temperature should be increased or decreased from 25°C to achieve spontaneity.
**Reactions:**
a. \( \text{N}_2\text{O}_4(g) \rightarrow 2 \text{NO}_2(g) \)
b. \( \text{NH}_4\text{Cl}(s) \rightarrow \text{HCl}(g) + \text{NH}_3(g) \)
c. \( 3 \text{H}_2(g) + \text{Fe}_2\text{O}_3(s) \rightarrow 2 \text{Fe}(s) + 3 \text{H}_2\text{O}(g) \)
d. \( \text{N}_2(g) + 3 \text{H}_2(g) \rightarrow 2 \text{NH}_3(g) \)
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