8.0 7.5 7.0 6.5 6.0 5.5 5.0 PPM.5 www 2.5 2.6 1.5 1.0 PPM 2H 2H al 3H 2H 15H 20 -1739.09 1172.87 2966.98 698.32 1458.44 1257.75 750.40 2876.43 1383.14 1889.92 3034.41 974.18 1498.88 1030 100

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For each problem, you must:
1) Calculate the degree of unsaturation.
-1
2) Assign the principal IR absorption bands above 1500 cm
3) Draw the structure of the compound
4) Label the protons on your structure with letters and assign them to peaks on the NMR spectrum
(see the example below).
OHD
4.0
C
2H
3.5
3.0
2.5
D
1H
3.0
This peak
is a magnified
version of
this peak
A
2.8
2.0
1H
B
zum
2.6
B
2H
Each problem contains the formula of the compound, the IR spectrum (with axes in cm³¹ vs. %
transmission), and the ¹H NMR spectrum (with axis in PPM shift). Some NMR spectra show a peak
hovering above the baseline. This is a magnified view of one of the actual peaks, to allow you to see
splitting more clearly.
1.5
2.4
A
3H
1.0 PPM
0.5
Transcribed Image Text:For each problem, you must: 1) Calculate the degree of unsaturation. -1 2) Assign the principal IR absorption bands above 1500 cm 3) Draw the structure of the compound 4) Label the protons on your structure with letters and assign them to peaks on the NMR spectrum (see the example below). OHD 4.0 C 2H 3.5 3.0 2.5 D 1H 3.0 This peak is a magnified version of this peak A 2.8 2.0 1H B zum 2.6 B 2H Each problem contains the formula of the compound, the IR spectrum (with axes in cm³¹ vs. % transmission), and the ¹H NMR spectrum (with axis in PPM shift). Some NMR spectra show a peak hovering above the baseline. This is a magnified view of one of the actual peaks, to allow you to see splitting more clearly. 1.5 2.4 A 3H 1.0 PPM 0.5
7.5 7.0 6.5 6.0 5.5 5.0 PPM.5
"чун "
2.5 2.6 1.5
1.6
2Н
2Н
ЗН
2Н
SH
-1739.08
1172.87
2966.98
698.32
1458.44
1257.75
750.40
2876.23
1383.14
1889.92
3834.41
1498.88
974.18
1030
100-
9: С1Н14Ог
Transcribed Image Text:7.5 7.0 6.5 6.0 5.5 5.0 PPM.5 "чун " 2.5 2.6 1.5 1.6 2Н 2Н ЗН 2Н SH -1739.08 1172.87 2966.98 698.32 1458.44 1257.75 750.40 2876.23 1383.14 1889.92 3834.41 1498.88 974.18 1030 100- 9: С1Н14Ог
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