8a. [8] Reactant R 8b. Describe from each what peaks correspond to the structures. [12] i. IR Spectrum ii. Mass Spectrum iii. 1H NMR iv. 13C NMR Product P 8. Use the spectrometric data to identify the type and write the reaction. [20] Reactant R IR Spectrum 1H NMR 3500 3000 2500 3.5 3.0 IR Spectrum 1H NMR qt 3500 2000 1500 1000 Wavenumber (cm) 2.5 8(ppm) 2500 Wavenumber (cm) Mass Spectrum RI 13C NMR 135.989 137.987 136.992 138.99 m/z 2.0 1.5 1.0 50 40 8(ppm) 30 20 Product Mass Spectrum 2000 1500 1000 500 dq RI 13C NMR 83.073 84.077 85.087 m/z 3.0 1.0 2.5 120 100 80 8(ppm) 60 40 20 8(ppm)

Principles of Instrumental Analysis
7th Edition
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Chapter11: Atomic Mass Spectrometry
Section: Chapter Questions
Problem 11.2QAP
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8a. [8]
Reactant R
8b. Describe from each what peaks correspond to the structures. [12]
i.
IR Spectrum
ii.
Mass Spectrum
iii.
1H NMR
iv.
13C NMR
Product P
Transcribed Image Text:8a. [8] Reactant R 8b. Describe from each what peaks correspond to the structures. [12] i. IR Spectrum ii. Mass Spectrum iii. 1H NMR iv. 13C NMR Product P
8. Use the spectrometric data to identify the type and write the reaction. [20]
Reactant R
IR Spectrum
1H NMR
3500
3000
2500
3.5
3.0
IR Spectrum
1H NMR
qt
3500
2000
1500
1000
Wavenumber (cm)
2.5 8(ppm)
2500
Wavenumber (cm)
Mass Spectrum
RI
13C NMR
135.989
137.987
136.992
138.99
m/z
2.0
1.5
1.0
50
40
8(ppm)
30
20
Product
Mass Spectrum
2000
1500
1000
500
dq
RI
13C NMR
83.073
84.077
85.087
m/z
3.0
1.0
2.5
120
100
80
8(ppm)
60
40
20
8(ppm)
Transcribed Image Text:8. Use the spectrometric data to identify the type and write the reaction. [20] Reactant R IR Spectrum 1H NMR 3500 3000 2500 3.5 3.0 IR Spectrum 1H NMR qt 3500 2000 1500 1000 Wavenumber (cm) 2.5 8(ppm) 2500 Wavenumber (cm) Mass Spectrum RI 13C NMR 135.989 137.987 136.992 138.99 m/z 2.0 1.5 1.0 50 40 8(ppm) 30 20 Product Mass Spectrum 2000 1500 1000 500 dq RI 13C NMR 83.073 84.077 85.087 m/z 3.0 1.0 2.5 120 100 80 8(ppm) 60 40 20 8(ppm)
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