8. In each of the following pairs, circle the quantity that is greater; if the two items are the same, circle SAME. a. electronegativity of chlorine electronegativity of arsenic # of unpaired electrons in As # of orbitals in 5p subshell # of 4p electrons in Se²- # of nonbonding domains on the central atom in T-shaped molecular geometry b. c. d. # of unpaired electrons in Mn² # of orbitals in 3p subshell # of 4p electrons in Rb or or or or e. # of nonbonding domains on the central atom in square pyramidal molecular geometry or 9 9 9 9 or or SAME SAME SAME SAME SAME

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Chapter9: Covalent Bonding: Orbitals
Section: Chapter Questions
Problem 57E: Use Figs. 4-54 and 4-55 to answer the following questions. a. Would the bonding molecular orbital in...
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Answer the following questions
8. In each of the following pairs, circle the quantity that is greater; if the two items are the same, circle SAME.
a.
electronegativity of chlorine
electronegativity of arsenic
# of unpaired electrons in As
# of orbitals in 5p subshell
# of 4p electrons in Se²-
# of nonbonding domains on the central
atom in T-shaped molecular geometry
9.
b.
sp²
c.
sp³d²
d.
a.
b.
C.
# of unpaired electrons in Mn²
e.
# of orbitals in 3p subshell
e.
# of nonbonding domains on the central
atom in square pyramidal molecular geometry
# of 4p electrons in Rb+
hybridization
of central atom
Spact
bond /
bond 4
or
or
The structure of lidocaine (C₁4H₂2N₂O), a common local anesthetic, is shown below. Answer the following questions
about this structure. Lone pairs of electrons have been omitted for clarity; all atoms (except H) obey the octet rule; bond
angles may not be as they appear.
Determine the number of sp2 hybridized atoms.
Determine the number of pi (x) bonds.
Consider the N-C-C bond angles labeled a and b. Which of these is the
larger angle? Circle the one best answer.
angle a
angle b
electron domain
geometry
or
trigonal planar
octahedral
or
trigonal
Biplamdal
or
330 21 653
Now consider the C-O bond labelled 3. also
What orbitals overlap to form the C- O sigma bond?
What orbitals overlap to form the C-O pi bond?
san bod (n)
they are the same
10. Fill in the blanks to complete the following table for substances with the chemical formula AX,.
#bonding
domains
they are the same length
d. Consider the CC bonds labelled 1 and 4. Which of these bonds should be shorter? Circle the one best answer
below.
-
#nonbonding
domains
0
HC
1
HC
CH₂
|4
orbital on C with
orbital on C with
or
molecular geometry
see-saw
or
or
or
or
SAME
CH₂
SAME
SAME
SAME
SAME
H₂C 2
orbital on O
orbital on O
polar or nonpolar?
polar
CH₂
POLAY
CH₂
Transcribed Image Text:8. In each of the following pairs, circle the quantity that is greater; if the two items are the same, circle SAME. a. electronegativity of chlorine electronegativity of arsenic # of unpaired electrons in As # of orbitals in 5p subshell # of 4p electrons in Se²- # of nonbonding domains on the central atom in T-shaped molecular geometry 9. b. sp² c. sp³d² d. a. b. C. # of unpaired electrons in Mn² e. # of orbitals in 3p subshell e. # of nonbonding domains on the central atom in square pyramidal molecular geometry # of 4p electrons in Rb+ hybridization of central atom Spact bond / bond 4 or or The structure of lidocaine (C₁4H₂2N₂O), a common local anesthetic, is shown below. Answer the following questions about this structure. Lone pairs of electrons have been omitted for clarity; all atoms (except H) obey the octet rule; bond angles may not be as they appear. Determine the number of sp2 hybridized atoms. Determine the number of pi (x) bonds. Consider the N-C-C bond angles labeled a and b. Which of these is the larger angle? Circle the one best answer. angle a angle b electron domain geometry or trigonal planar octahedral or trigonal Biplamdal or 330 21 653 Now consider the C-O bond labelled 3. also What orbitals overlap to form the C- O sigma bond? What orbitals overlap to form the C-O pi bond? san bod (n) they are the same 10. Fill in the blanks to complete the following table for substances with the chemical formula AX,. #bonding domains they are the same length d. Consider the CC bonds labelled 1 and 4. Which of these bonds should be shorter? Circle the one best answer below. - #nonbonding domains 0 HC 1 HC CH₂ |4 orbital on C with orbital on C with or molecular geometry see-saw or or or or SAME CH₂ SAME SAME SAME SAME H₂C 2 orbital on O orbital on O polar or nonpolar? polar CH₂ POLAY CH₂
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